zinc(II) bis(2-benzoxazolyl)methanate | 254117-21-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并恶唑类
• 英文名称: zinc(II) bis(2-benzoxazolyl)methanate
• CAS: 254117-21-0
• 化学式: C₃₀H₁₈N₄O₄Zn
• 分子量: 563.887
• InChiKey: IMRRIDVDHREESL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,1-bisbenzoxazolylmethane 、 zinc diacetate 以 甲醇 为溶剂， 生成 zinc(II) bis(2-benzoxazolyl)methanate
  参考文献：
  名称：

  A spectroscopic and magnetic study of complexes of bis(2–benzothiazolyl)methanate and bis(2–benzoxazolyl) methanate with Co(II), Ni(II), Cu(II) and Zn(II)

  摘要：

  The co-ordination geometry of the complexes M(bbtm)2 and M(bbom)2 (M: Co, Ni, Cu, Zn; bbtm, bis(2-benzothiazolyl)methanate; bbom, bis(2-benzoxazolyl)methanate) are discussed on the basis of their IR, Raman, resonance Raman, electronic and ESR spectra. Compounds of Ni, Co, Zn with both ligands and Cu(bbom)2 resulted to have a distorted tetrahedral geometry. The distortion towards a square planar geometry is more marked for the M(bbtm)2 series than for the M(bbom)2 one. It has been impossible to suggest a co-ordination geometry for Cu(bbtm)2, that probably has a polymeric structure.

  DOI：

  10.1016/s1386-1425(99)00277-2