2-benzyldodecanoic acid | 119191-45-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 苯丙酸
• 英文名称: 2-benzyldodecanoic acid
• 英文别名: 2-Benzyl-dodecansaeure
• CAS: 119191-45-6
• 化学式: C₁₉H₃₀O₂
• 分子量: 290.446
• InChiKey: NWVQWDXNECNOMJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  21
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.63
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-benzyldodecanoic acid 在 9-均三甲苯基-2,7,10-三甲基吖啶高氯酸盐 、 [Co(dimethylglyoxime)₂(N-methyl-imidazole)Cl] 、 三乙酰氧基硼氢化钠 、 sodium carbonate 作用下， 以 甲醇 、 水 为溶剂， 反应 16.0h， 以42%的产率得到
  参考文献：
  名称：

  光氧化还原/钴双催化脱羧羧酸的消除：发展和机理的见解。

  摘要：

  近来，用于羧酸脱羧消除的双重催化策略已引起关注。我们的实验室以前曾报道过光氧化还原/钴肟双催化方法，该方法可直接从N酰基氨基酸合成酰胺和烯甲酸酯，并避免使用任何化学计量试剂。本文详述的进一步开发改进了这种转化的用途，进一步的实验为反应机理提供了新的见解。这些新的发展和见识有望帮助扩大光氧化还原/钴双催化系统。

  DOI：

  10.1002/chem.202001952
• 作为产物：
  描述：

  苄基丙二酸二乙酯 在 sodium hydroxide 作用下， 生成 2-benzyldodecanoic acid
  参考文献：
  名称：

  Ukita et al., Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1951, vol. 71, p. 289,291

  摘要：

  DOI：

文献信息

• NON-ABSORBENT AND ABSORBENT ARTICLES FOR INHIBITING THE PRODUCTION OF EXOPROTEINS
  申请人：KIMBERLY-CLARK WORLDWIDE, INC.

  公开号：EP1793871A2

  公开（公告）日：2007-06-13
• Absorbent articles for inhibiting the production of exoproteins
  申请人：Syverson Ellen Rae

  公开号：US20060067990A1

  公开（公告）日：2006-03-30

  Absorbent articles for inhibiting the production of exoproteins from Gram positive bacteria are disclosed. The absorbent articles include an effective amount of a precursor compound having the general formula: wherein R 1 is selected from the group consisting of R 7 is —OCH 2 —; X is 0 or 1; R 5 is a substituted or unsubstituted aromatic ring or a monovalent saturated or unsaturated, substituted or unsubstituted, branched or straight chain hydrocarbyl moiety that may or may not be substituted with hetero atoms; R 6 is selected from the group consisting of an amino acid, a methyl ester of an amino acid, and an ethyl ester of an amino acid; R 2 , R 3 , and R 4 are independently selected from the group consisting of H, OH, COOH.
• Non-absorbent articles for inhibiting the production of exoproteins
  申请人：Syverson Ellen Rae

  公开号：US20060067991A1

  公开（公告）日：2006-03-30

  Non-absorbent articles for inhibiting the production of exoproteins from Gram positive bacteria are disclosed. The non-absorbent articles include an effective amount of a precursor compound having the general formula: wherein R 1 is selected from the group consisting of R 7 is —OCH 2 —; X is 0 or 1; R 5 is a substituted or unsubstituted aromatic ring or a monovalent saturated or unsaturated, substituted or unsubstituted, branched or straight chain hydrocarbyl moiety that may or may not be substituted with hetero atoms; R 6 is selected from the group consisting of an amino acid, a methyl ester of an amino acid, and an ethyl ester of an amino acid; R 2 , R 3 , and R 4 are independently selected from the group consisting of H, OH, COOH.
• PERSONAL CARE COMPOSITIONS COMPRISING MALODOR REDUCTION COMPOSITIONS
  申请人：The Procter & Gamble Company

  公开号：US20160089318A1

  公开（公告）日：2016-03-31

  The present invention relates to personal care compositions comprising malodor reduction compositions and methods of making and using such personal care compositions. Such personal care compositions comprising the malodor control technologies disclosed herein provide malodor control without leaving an undesirable scent and when perfume is used to scent such compositions, such scent is not unduly altered by the malodor control technology.
• [EN] NON-ABSORBENT AND ABSORBENT ARTICLES FOR INHIBITING THE PRODUCTION OF EXOPROTEINS<br/>[FR] ARTICLES NON ABSORBANTS ET ABSORBANTS INHIBANT LA PRODUCTION D'EXOPROTEINES
  申请人：KIMBERLY CLARK CO

  公开号：WO2006038980A2

  公开（公告）日：2006-04-13

  Non-absorbent and absorbent articles for inhibiting the production of exoproteins from Gram positive bacteria are disclosed. The non-absorbent and absorbent articles include an effective amount of a precursor compound having the general formula (I): wherein R1 is selected from the group consisting of formula (II) and formula (III); R7 is -OCH2-; X is 0 or 1; R5 is a substituted or unsubstituted aromatic ring or a monovalent saturated or unsaturated, substituted or unsubstituted, branched or straight chain hydrocarbyl moiety that may or may not be substituted with hetero atoms; R6 is selected from the group consisting of an amino acid, a methyl ester of an amino acid, and an ethyl ester of an amino acid; R2, R3, and R4 are independently selected from the group consisting of H, OH, COOH.