| 155831-41-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫吡喃类
• CAS: 155831-41-7
• 化学式: C₂₄H₄₂O₄S₂W₂
• 分子量: 826.427
• InChiKey: MXAWYPNAEGQRIX-FHWLGTNKSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  7.62
• 重原子数：
  32.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  36.92
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  、 叔丁醇 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Stepwise activation of σ-thienyl ligands at di-tungsten centres

  摘要：

  将Ï-2-噻吩基和Ï-2-苯并噻吩基配体（但不是Ï-3-噻吩基配体）连接到含有 W26+ 的中心，可逐步打开五元环，在叔丁醇的存在下，生成 W2(OBut)5(µ-SC4H3)(Î-1-2-SC4H3) 中的新型硫醇-µ-亚烷基金属环，该金属环的结构已经定性；中间体 W2(OBut)4(µ-SC4H3)(δ-1-2-SC4H3)，其中含有一个桥接的硫醇亚乙烯基金属环，已通过核磁共振光谱进行了表征。

  DOI：

  10.1039/c39940000683
• 作为产物：
  描述：

  、 叔丁醇 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Stepwise activation of σ-thienyl ligands at di-tungsten centres

  摘要：

  将Ï-2-噻吩基和Ï-2-苯并噻吩基配体（但不是Ï-3-噻吩基配体）连接到含有 W26+ 的中心，可逐步打开五元环，在叔丁醇的存在下，生成 W2(OBut)5(µ-SC4H3)(Î-1-2-SC4H3) 中的新型硫醇-µ-亚烷基金属环，该金属环的结构已经定性；中间体 W2(OBut)4(µ-SC4H3)(δ-1-2-SC4H3)，其中含有一个桥接的硫醇亚乙烯基金属环，已通过核磁共振光谱进行了表征。

  DOI：

  10.1039/c39940000683

文献信息

• Ring-Opening of σ-Thienyl and σ-Furyl Ligands at Ditungsten (M⋮M) Centers
  作者：Malcolm H. Chisholm、Scott T. Haubrich、John C. Huffman、William E. Streib

  DOI：10.1021/ja962978v

  日期：1997.2.1

  A series of compounds of formula 1,2-M(2)(sigma-Th)(2)(NMe(2))(4), 1, has been prepared, where M = Mo and/or W and Th = 2-thienyl[2-Th], 3-thienyl[3-Th], 5-methyl-2-thienyl[2,5-MeTh], and 2-benzothienyl[2-BTh]. In hydrocarbon solvents-these compounds exist as a mixture of anti and gauche rotamers having a central CN(2)M=MN(2)C core. Addition of (t)BuOH or CF(3)Me(2)COH to hydrocarbon solutions of 1, where M = W, lead to ring-opened products, 2, when the thienyl ligand is attached via the 2-carbon position. No ring-opening occurs for 3-thienyl derivatives. W-2(OR)(5) (mu-CCH2CHCHS) (sigma-2-Th), 2, where one of the 2-thienyl rings has been opened, has been fully characterized and shown to be derived from a ring-opened mu-vinylidene intermediate W-2(O(t)Bu)(4)(mu-CCHCHCHS)(sigma-2-Tn). Rather interestingly, the compound W-2(sigma-2-Th)(NMe(2))(5) reacts with (t)BuOH to give only W-2(2-Th)(O(t)Bu)(5) and HNMe(2). Reactions between 1 and the less sterically demanding alcohols (PrOH)-Pr-i and (t)BuCH(2)OH lead to W-2(OR)(6) compounds with liberation of HNMe(2) and the sulfur containing hydrocarbon. Compound 1 (M = W, 2-Th) reacts with CO2 to give W-2(NMe(2))(2)(O-2(NMe(2))(2)(sigma 2-Th)(2), 3, while with pivalic anhydride W-2(O(2)C(t)Bu)(4) is formed via reductive elimination of the C-C coupled product 2,2'-bithiophene and (t)BuCONMe(2) (4 equiv). 1 (M = W, 2-Th) and CO yield a product formulated as W-2(NMe(2))(4)(mu-CCHCHCHS)(sigma-2-Th)(CO)(3) wherein one ring has opened to form a mu-vinylidene thiolate Ligand. Attempts to prepare 1,2-W(2)L(2)(NMe(2))(4) compounds are described where L = an eta(1)- nitrogen containing heterocycle but only for L = 2-methylindolyl was a compound successfully characterized, Reactions of these compounds with (t)BuOH gave W-2(O(t)Bu)(6) and LH (2 equiv). The compound W-2(sigma-2-FU)(2)(NMe(2))(4) was prepared and characterized (2-Fu = 2-furyl) and shown to undergo ring-opening in its reaction with (t)BuOH to give W-2(O(t)Bu)(5)(mu u-CCH2CHCHO) (sigma-2-Fu), 4, in an analogous manner to the 2-Th complex. The complexes 1 (M = W, 2-Th), 2, 3, and 4 have been characterized by single crystal X-ray studies. The results described herein are compared to other ring-opening reactions of S, N, and O organic heterocyclic compounds as models for the activation of S, N, and O containing fossil fuels in hydrodesulfurization (HDS), hydrodenitrogenation (HDN), and hydrodeoxygenation (HDO) processes. The cleavage of the C-X bonds at the (M=M)(6+) centers (M = Mo, W and X = S, N and O) is also compared with earlier cleavage reactions involving C=O, RC=N, R(2)C=O, and Ar2C=S compounds.