ethylsulfanylethane;trichlororhodium | 14784-72-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: ethylsulfanylethane;trichlororhodium
• CAS: 14784-72-6；27770-56-5；34177-73-6
• 化学式: C₁₂H₃₀Cl₃RhS₃
• 分子量: 479.833
• InChiKey: FGUZWYLPZMPNGK-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  7.34
• 重原子数：
  19.0
• 可旋转键数：
  9.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  ethylsulfanylethane;trichlororhodium 在 pyridine 作用下， 以 苯 为溶剂， 生成 Rh(S(C2H5)2)2(pyridine)Cl3
  参考文献：
  名称：

  Kochetkova, A. P.; Sveshnikova, L. B.; Stepanovich, V. M., Russian Journal of Inorganic Chemistry, 1981, vol. 26, p. 1340 - 1343

  摘要：

  DOI：
• 作为产物：
  描述：

  乙硫醚 、 rhodium(III) chloride trihydrate 以 甲醇 为溶剂， 以71%的产率得到ethylsulfanylethane;trichlororhodium
  参考文献：
  名称：

  Studies on the Activation and Hydrosilylation Catalysis of RhCl₃(Bu₂S)₃

  摘要：

  RhCl3(Bu2S)(3) is an industrial precatalyst utilized in the curing of some solventless silicone-release coatings formulations. The catalyst requires no additional inhibitor, in contrast to typical Pt formulations, and so questions arose about how fast the catalyst could trigger curing if it were used in a more activated form. Studies on the activation of RhCl3(Bu2S)(3) revealed multiple intermediates, of which [RhCl(Bu2S)(2)](2) and [RhHCl(SiMe(OSiMe3)(2)) (Bu2S)(2)](2) were isolated. [RhHCl(SiMe(OSiMe3)(2))(Bu2S)(2)](2) is the most activated form of the precatalyst, showing a brief induction period. Various experiments were performed to analyze the nature of the catalyst, including Hg poisoning, addition of poison ligands, and comparisons versus Rh nanoparticles. The data tend to be more consistent with a molecular catalyst than Rh nanoparticles. Data are also provided that support the active catalyst containing a RhxClx(Bu2S)(2x) fragment, although the exact identity of the active catalyst is not yet determined.

  DOI：

  10.1021/acs.inorgchem.7b00029

文献信息

• Complexes of platinum(II), platinum(IV), rhodium(III) and iridium(III) containing orthometallated triphenylphosphine
  作者：Martin A. Bennett、Suresh K. Bhargava、Mingzhe Ke、Anthony C. Willis

  DOI：10.1039/b004908p

  日期：——

  atoms. Oxidative addition of methyl iodide or iodine to [PtC6H4(PPh2)-2}2] gives initially platinum(IV) complexes [PtI(R)C6H4(PPh2)-2}2] (R = Me or I) in which the added groups are mutually trans; in the final, stable products the added groups and the phosphorus atoms are, separately, mutually cis. Oxidative addition of bromine to [PtC6H4(PPh2)-2}2] gives initially trans-[PtBr2C6H4(PPh2)-2}2] but

  用2-LiC 6 H 4 PPh 2处理[PTCl 2（SEt 2）2 ]或[RhCl 3（SEt 2）3 ]，得到四元环螯合物芳基铂（II）或芳基铑（III）络合物[ PT C 6 H 4（P Ph 2）-2} 2 ]和[ Rh C 6 H 4（P Ph 2）-2} 3 ]，而相应的[IrCl 3（SEt 2）3 ]给出了Ir-C 6 H 4（PPh 2）键断裂产生的IrCl C 6 H 4（P Ph 2）-2} 2（PPh 3）] 。[ PT C 6 H 4（P Ph 2）-2} 2 ]的化学性质主要是由PT–P键的不稳定性所决定的，这些键依次被配体在室温下，得到含有单齿Ç络合物6 ħ 4（PPH 2），即[铂C 6 H ^ 4（P博士2）-2} η 1 -C 6 ħ 4（PPH 2）-2}（L ）] [L = PPH 3，P（OPH）3，P（OME）3或卜吨] NC和[PT
• Complexes with ligands containing group VB and VIB atoms. Part IV. Dialkyl sulphide complexes of rhodium(III) and iridium(III) halides
  作者：E. A. Allen、W. Wilkinson

  DOI：10.1039/dt9720000613

  日期：——

  dialkyl sulphide) has been carried out. The use of simple sulphides, L = Me2S, Et2S, C4H8S, or C5H10S resulted in the formation of stable, crystalline solids facilitating the assignment of stereochemistry. I.r., u.v., 1H n.m.r., and dipole moment measurements have been used to clearly show that the compounds obtained by the reaction of the appropriate metal halide with the dialkyl sulphide all have

  进行了MX 3 L 3型化合物的结构研究（M = Rh或Ir； X = Cl，Br或I； L =硫化二烷基）。使用简单的硫化物L = Me 2 S，Et 2 S，C 4 H 8 S或C 5 H 10 S导致形成稳定的结晶固体，从而促进了立体化学的归属。Ir，uv，1 H nmr和偶极矩测量已清楚地表明，通过适当的金属卤化物与二烷基硫醚反应制得的化合物均具有常见的八面体子午线构型。
• Anderson, S. J.; Barnes, J. R.; Goggin, P. L., 1978, p. 286 - 287
  作者：Anderson, S. J.、Barnes, J. R.、Goggin, P. L.、Goodfellow, R. J.

  DOI：——

  日期：——
• Anderson, S. J.; Barnes, J. R.; Goggin, P. L., Journal of Chemical Research, Miniprint, 1978, p. 3601 - 3628
  作者：Anderson, S. J.、Barnes, J. R.、Goggin, P. L.、Goodfellow, R. J.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Rh: SVol.B3, 1.1.3.1.4, page 7 - 8
  作者：

  DOI：——

  日期：——