(butyl dithiocarbonate)(benzaldehyde benzoylhydrazone anion)nickel(II) | 771488-27-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (butyl dithiocarbonate)(benzaldehyde benzoylhydrazone anion)nickel(II)
• CAS: 771488-27-8
• 化学式: C₁₉H₂₀N₂NiO₂S₂
• 分子量: 431.202
• InChiKey: WXNIJLUUKQXOHQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (butyl dithiocarbonate)(benzaldehyde benzoylhydrazone anion)nickel(II) 以 neat (no solvent) 为溶剂， 生成 nickel(II) oxide
  参考文献：
  名称：

  Synthesis and Investigation of Mixed‐Ligand Transition Metal Complexes of Alkyl Dithiocarbonate and Benzoylhydrazine or Benzoylhydrazone Derivatives

  摘要：

  Mixed-ligand complexes of the types [Ni(Etdtcn)(BH)], [Ni(Budtcn) (BeBH)], and [M(Rdtcn)(salBH)], where M = Co(II), Ni(II), or Cu(II); R = methyl (Me), ethyl (Et), propyl (Prop) or butyl of the dithiocarbonate (Bu); dtcn = dithiocarbonate group; BH = benzoyl-hydrazine anion, BeBH = benzaldehyde benzoylhydrazone anion, and salBH = salicylaldehyde benzoylhydrazone anion have been synthesised. Elemental analyses, molar conductivities, and spectral (IR, UV, and mass) studies have been used to elucidate the structure of the metal complexes. HBH and HBeBH coordinate in the enol form as bidentate ligands forming a square-planar structure around Ni(II). Moreover, the HsalBH ligand behaves as tridentate anion with all metal ions and an octahedral structure for these complexes is proposed. The three ligands and some of their complexes were screened against three species of bacteria, namely B. cereus (G +ve), Ap. aeruginosa (G -ve), and S. aureus (G +ve) and five types of fungi, A. flavus, A. fumigatus var. albus, A. niger, F. oxysporum or C. tropicum. The HsalBH ligand has shown high activity against bacteria and fungi, probably due to the presence of a hydroxyl group in this ligand.

  DOI：

  10.1081/sim-120035954
• 作为产物：
  描述：

  N-苯甲酰基-N'-苄亚基肼 、 丁基黄原酸钾 、 nickel dichloride 以 乙醇 、 水 为溶剂， 以60%的产率得到(butyl dithiocarbonate)(benzaldehyde benzoylhydrazone anion)nickel(II)
  参考文献：
  名称：

  Synthesis and Investigation of Mixed‐Ligand Transition Metal Complexes of Alkyl Dithiocarbonate and Benzoylhydrazine or Benzoylhydrazone Derivatives

  摘要：

  Mixed-ligand complexes of the types [Ni(Etdtcn)(BH)], [Ni(Budtcn) (BeBH)], and [M(Rdtcn)(salBH)], where M = Co(II), Ni(II), or Cu(II); R = methyl (Me), ethyl (Et), propyl (Prop) or butyl of the dithiocarbonate (Bu); dtcn = dithiocarbonate group; BH = benzoyl-hydrazine anion, BeBH = benzaldehyde benzoylhydrazone anion, and salBH = salicylaldehyde benzoylhydrazone anion have been synthesised. Elemental analyses, molar conductivities, and spectral (IR, UV, and mass) studies have been used to elucidate the structure of the metal complexes. HBH and HBeBH coordinate in the enol form as bidentate ligands forming a square-planar structure around Ni(II). Moreover, the HsalBH ligand behaves as tridentate anion with all metal ions and an octahedral structure for these complexes is proposed. The three ligands and some of their complexes were screened against three species of bacteria, namely B. cereus (G +ve), Ap. aeruginosa (G -ve), and S. aureus (G +ve) and five types of fungi, A. flavus, A. fumigatus var. albus, A. niger, F. oxysporum or C. tropicum. The HsalBH ligand has shown high activity against bacteria and fungi, probably due to the presence of a hydroxyl group in this ligand.

  DOI：

  10.1081/sim-120035954