| 204859-45-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• CAS: 204859-45-0
• 化学式: C₁₂H₁₇NO₂
• 分子量: 207.272
• InChiKey: HMWATXDHEISOCQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.15
• 重原子数：
  15.0
• 可旋转键数：
  5.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  52.82
• 氢给体数：
  2.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  copper(II) sulfate 、 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Study of bonding characteristics of some new metal complexes of salicylaldoxime (SALO) and its derivatives by far infrared and UV spectroscopy

  摘要：

  New metal chelates of copper, lead and zinc with salicylaldoxime (SALO) and its derivatives have been prepared. The chelates have been characterized by elemental analysis, atomic absorption, infrared and UV spectroscopy. SALO behaves as a bidentate ligand forming neutral metal chelates through the phenolic oxygen and the oxime nitrogen. The M-O stretching frequencies for the transition metals show good agreement with the Irving-William's stability order Cu > Zn > Pb. Similar trend is seen for the M-N stretching frequencies in IR and the shift in transitions from UV spectral data for the metal chelates. (C) 1998 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(97)00221-7
• 作为产物：
  描述：

  1-(2-羟基苯基)己烷-1-酮 在 吡啶 、 盐酸羟胺 作用下， 生成
  参考文献：
  名称：

  Study of bonding characteristics of some new metal complexes of salicylaldoxime (SALO) and its derivatives by far infrared and UV spectroscopy

  摘要：

  New metal chelates of copper, lead and zinc with salicylaldoxime (SALO) and its derivatives have been prepared. The chelates have been characterized by elemental analysis, atomic absorption, infrared and UV spectroscopy. SALO behaves as a bidentate ligand forming neutral metal chelates through the phenolic oxygen and the oxime nitrogen. The M-O stretching frequencies for the transition metals show good agreement with the Irving-William's stability order Cu > Zn > Pb. Similar trend is seen for the M-N stretching frequencies in IR and the shift in transitions from UV spectral data for the metal chelates. (C) 1998 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(97)00221-7