Ni(salicylideneanthranilic acid-2H)(2,4,6-tris(2-pyridyl)-1,3,5-triazine) | 934390-19-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Ni(salicylideneanthranilic acid-2H)(2,4,6-tris(2-pyridyl)-1,3,5-triazine)
• 英文别名: Ni(SAA)(TPTZ)
• CAS: 934390-19-9
• 化学式: C₃₂H₂₁N₇NiO₃
• 分子量: 610.254
• InChiKey: BEPRDSIKPWDMIK-WNTOMBHQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 salicylidene anthranilic acid potassium salt 、 2,4,6-三(2-吡啶基)三嗪 以 甲醇 为溶剂， 以75%的产率得到Ni(salicylideneanthranilic acid-2H)(2,4,6-tris(2-pyridyl)-1,3,5-triazine)
  参考文献：
  名称：

  Synthesis, characterization and superoxide dismutase activity of some octahedral nickel(II) complexes

  摘要：

  Four new mixed ligand nickel(II) complexes viz., [Ni(tren)(phen)](ClO4)(2) (1), [Ni(tren)(bipy)]ClO4)(2) (2), [Ni(SAA)(PMDT)] center dot 2H(2)O (3) and [Ni(SAA)(TPTZ)] (4) (tren = tris(2-aminoethylamine), phen = 1,10-phenanthroline, bipy = 2,2'-bipyridine, SAA = salicylidene anthranilic acid, PMDT = N,N,N',N '',N ''-pentamethyldiethylenetriamine, TPTZ = 2,4,6-tri(2-pyridyl)-1,3,5-triazine) have been synthesized and characterized by means of elemental analysis, spectroscopic, magnetic susceptibility and cyclic voltammetric measurements. Single crystal X-ray analysis of [Ni(tren)(phen)](ClO4)(2) (1) and [Ni(SAA)(PMDT)] center dot 2H(2)O (3) has revealed the presence of a distorted octahedral geometry. Superoxide dismutase activity of these complexes has also been measured. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.09.041