N,N,N',N'-tetrakis[(1-methylimidazol-2-yl)methyl]-1,3-diaminopropan-2-ol | 177338-21-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N',N'-tetrakis[(1-methylimidazol-2-yl)methyl]-1,3-diaminopropan-2-ol
• 英文别名: N,N,N',N'-tetrakis(2-methylimidazolyl)-2-hydroxy-1,3-diaminopropane；1,3-Bis[bis[(1-methylimidazol-2-yl)methyl]amino]propan-2-ol
• CAS: 177338-21-5
• 化学式: C₂₃H₃₄N₁₀O
• 分子量: 466.589
• InChiKey: YSSOGXOTSZMRJL-UHFFFAOYSA-N

物化性质

• 沸点：
  756.4±60.0 °C(Predicted)
• 密度：
  1.27±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -1.8
• 重原子数：
  34
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  98
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  copper(II) perchlorate hexahydrate 、 N,N,N',N'-tetrakis[(1-methylimidazol-2-yl)methyl]-1,3-diaminopropan-2-ol 、 sodium trideuterioacetate 在 Et₃N 作用下， 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  双核铜（II）配合物结合了新的单独的聚咪唑配体。

  摘要：

  双核铜（II）络合物[Cu（2）（tmihpn）（prz）]（ClO（4））（2）.2CH（3）CN（6）和[Cu（2）（tmihpn）（O（2） ）CCH（3））]（ClO（4））（2）.CH（3）CN（7）被制备，其中tmihpn是N，N，N'，N'-四[[1-甲基咪唑-2-基）甲基] -1,3-二氨基丙烷-2-醇，prz是吡唑根阴离子。确定了6和7的晶体结构，结果表明这两种配合物均包含桥连的醇盐配体以及桥连的吡唑酸酯和乙酸根离子。晶体数据：化合物6，三斜晶系，P＆onemacr ;, a = 18.089（2）Å，b = 22.948（3）Å，c = 9.597（2）Å，α= 93.37（2）度，beta = 94.49（2）度，γ= 81.69（2）度，V = 3925.1Å（3），Z = 4；化合物7，三斜晶，P＆onemacr ;, a = 12.417（2）Å，b = 15.012（3）Å，c

  DOI：

  10.1021/ic9511985

文献信息

• New functional models for catechol oxidases
  作者：Pavel Gentschev、Niclas Möller、Bernt Krebs

  DOI：10.1016/s0020-1693(99)00553-8

  日期：2000.4

  The new dinuclear copper(II) complexes [Cu-2(L1)(mu-OAc)](ClO4)(2). CH3CN (1), [Cu-2(L2)(CH3CN)(2)](ClO4)(4). C2H5OH (2), [Cu-2(L3)(2)(CH3CN)(2)](PF6)(2) (3) and [Cu-2(L4)(2)](PF6)(2). CH2Cl2 (4) were prepared with the ligands N,N,N',N'-tetrakis((N-2-hydroxy-ethyl)-2-benzimidazolylmethyl)-2-hydroxy-1,3-diaminopropane HL1, N,N,N',N'-tetrakis (2-methylimidazolyl)-2-hydroxy-1,3-diaminopropane HL2, (2-pyridylmethyl)(1-hydroxypropyl)amine HL3 and (2-hydroxybenzyl)(N,N-dimethylpropyl)amine HL4. All complexes were characterized by X-ray structure determination, revealing dinuclear cations and perchlorate or hexafluorophosphate counter ions. In the complex cations the two copper(II) atoms show different coordination spheres with N4O, N3O2 or N2O2 donor sets and different bridging systems. The Cu ... Cu distances vary from 2.918(2) to 4.756(2) Angstrom. The catalytic performance of the oxidation of 3,5-di-tert-butylcatechol to quinone was studied using UV-Vis absorption spectra methods. Complex 3 exhibits the highest activity with a turnover number of 32 h(-1) while the other compounds show lower rates of oxidation. A kinetic treatment on the basis of the Michaelis-Menten model was applied. (C) 2000 Elsevier Science S.A. All rights reserved.
• MODIFIED POLYMER COMPLEX, COMPLEX MONOMER, POLYMER COMPLEX, AND REDOX,CATALYST
  申请人：Ishiyama Takeshi

  公开号：US20100197886A1

  公开（公告）日：2010-08-05

  A modified polymer complex, which is obtained by intermolecular and/or intramolecular crosslinking of a polymer complex via side chains thereof, wherein the polymer complex is a copolymer of a complex monomer meeting the following conditions (i) to (iii) and a comonomer expressed by the following general formula (1): R 02 R 03 ═R 01 E (The definitions of R 01 , R 02 , R 03 and E are omitted.) (i) the complex monomer has two or more transition metal atoms; (ii) the complex monomer has a polydentate ligand containing three or more coordinating atoms that are coordinately bonded to the transition metal atoms; and (iii) the polydentate ligand has one or more polymerizable functional groups.
• US7335629B2
  申请人：——

  公开号：US7335629B2

  公开（公告）日：2008-02-26