6-[4-[6-Hydroxy-5-(2-hydroxy-3-phenylnaphthalen-1-yl)-7-phenylnaphthalen-2-yl]phenyl]-1-(2-hydroxy-3-phenylnaphthalen-1-yl)-3-phenylnaphthalen-2-ol | 1158868-68-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 6-[4-[6-Hydroxy-5-(2-hydroxy-3-phenylnaphthalen-1-yl)-7-phenylnaphthalen-2-yl]phenyl]-1-(2-hydroxy-3-phenylnaphthalen-1-yl)-3-phenylnaphthalen-2-ol
• CAS: 1158868-68-8
• 化学式: C₇₀H₄₆O₄
• 分子量: 951.133
• InChiKey: RAZVWCWPTMHLSA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.5
• 重原子数：
  74
• 可旋转键数：
  8
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.9
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,4-bis(2,2'-bis(methoxymethoxy)-3,3'-diphenyl-[1,1'-binaphthalen]-6-yl)benzene 在 盐酸 、 水 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 反应 20.0h， 以95%的产率得到6-[4-[6-Hydroxy-5-(2-hydroxy-3-phenylnaphthalen-1-yl)-7-phenylnaphthalen-2-yl]phenyl]-1-(2-hydroxy-3-phenylnaphthalen-1-yl)-3-phenylnaphthalen-2-ol
  参考文献：
  名称：

  Self-supported BINOL–Zn catalysts for heterogeneous enantioselective epoxidation of (E)-α,β-unsaturated ketones

  摘要：

  A class of chiral self-supported catalysts prepared from bis-BINOL ligands and diethyl zinc were successfully applied in the hetereogeneous enantioselective epoxidation of a range of (E)-alpha,beta-unsaturated ketones, affording the corresponding epoxy ketones in high enantioselectivity. The self-supported catalysts were easily recovered from the reaction mixture and were reusable for several consecutive runs. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2009.02.151