[Pb2(μ3-4-amino-1-naphthalenesulfonic acid)2(μ2-Cl)2(H2O)2]n | 1621007-92-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [Pb2(μ3-4-amino-1-naphthalenesulfonic acid)2(μ2-Cl)2(H2O)2]n
• 英文别名: [Pb2(μ₃-4-amino-1-naphthalenesulfonic acid)₂(μ₂-Cl)₂(H₂O)₂]n
• CAS: 1621007-92-8
• 化学式: C₁₀H₈NO₃S*Cl*H₂O*Pb
• 分子量: 482.913
• InChiKey: SMGJDPMZIDHYCL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.88
• 重原子数：
  18.0
• 可旋转键数：
  1.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  114.72
• 氢给体数：
  1.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  [Pb2(μ3-4-amino-1-naphthalenesulfonic acid)2(μ2-Cl)2(H2O)2]n 在 air 作用下， 反应 5.0h， 生成 lead oxide sulfate
  参考文献：
  名称：

  Holodirected coordination sphere around lead(II) in three-dimensional polymeric structure; New precursor for preparation of lead oxide sulfate nano-structures

  摘要：

  A new lead(II) three-dimensional coordination polymer, [Pb-2(mu(3)-ANS)(2)(mu(2)-Cl)(2)(H2O)(2)](n) (1) [ANS(-) = 4-amino-1 -naphthalenesulfonateb has been synthesized and characterized. The single-crystal X-ray data of compound 1 shows only one type of Pb-II ion with coordination number of six, the lead atom has distorted octahedral coordination sphere containing stereo-chemically inactive electron lone pair. The thermal stability of 1 was studied by TG-DTA (Thermo gravimetric and differential thermal analyses). Regular morphology of Pb-2(SO4)O nano-particle was prepared from fine powders of compound 1 by calcination process at 700 degrees C. This nano-structure was characterized by XRD (X-ray powder diffraction) and SEM (Scanning electron microscopy). (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2014.06.004
• 作为产物：
  描述：

  lead(II) nitrate 、 potassium chloride 、 水 、 sodium 4-amino-1-naphthalenesulfonate 反应 3.0h， 以47%的产率得到[Pb2(μ3-4-amino-1-naphthalenesulfonic acid)2(μ2-Cl)2(H2O)2]n
  参考文献：
  名称：

  Holodirected coordination sphere around lead(II) in three-dimensional polymeric structure; New precursor for preparation of lead oxide sulfate nano-structures

  摘要：

  A new lead(II) three-dimensional coordination polymer, [Pb-2(mu(3)-ANS)(2)(mu(2)-Cl)(2)(H2O)(2)](n) (1) [ANS(-) = 4-amino-1 -naphthalenesulfonateb has been synthesized and characterized. The single-crystal X-ray data of compound 1 shows only one type of Pb-II ion with coordination number of six, the lead atom has distorted octahedral coordination sphere containing stereo-chemically inactive electron lone pair. The thermal stability of 1 was studied by TG-DTA (Thermo gravimetric and differential thermal analyses). Regular morphology of Pb-2(SO4)O nano-particle was prepared from fine powders of compound 1 by calcination process at 700 degrees C. This nano-structure was characterized by XRD (X-ray powder diffraction) and SEM (Scanning electron microscopy). (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2014.06.004