4-甲基-2-(2-甲基丙基)-1,3-二恶烷 | 3080-75-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶烷
• 中文名称: 4-甲基-2-(2-甲基丙基)-1,3-二恶烷
• 中文别名: 丝氨酸,2-甲基-,甲基酯
• 英文名称: 2-Isobutyl-4-methyl-1,3-dioxane
• 英文别名: 4-methyl-2-(2-methylpropyl)-1,3-dioxane
• CAS: 3080-75-9
• 化学式: C₉H₁₈O₂
• 分子量: 158.24
• InChiKey: ZFBLKHRAGAMZDX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-甲基-2-(2-甲基丙基)-1,3-二恶烷 、 三辛基铝 生成 3-(2-methyldodecan-4-yloxy)butan-1-ol
  参考文献：
  名称：

  Ishihara Kazuaki, Hanaki Naoyuki, Yamamoto Hisashi, J. Amer. Chem. Soc., 115 (1993) N 23, S 10695-10704

  摘要：

  DOI：
• 作为产物：
  描述：

  1,3-丁二醇 、 异戊醛 生成 4-甲基-2-(2-甲基丙基)-1,3-二恶烷
  参考文献：
  名称：

  Ishihara Kazuaki, Hanaki Naoyuki, Yamamoto Hisashi, J. Amer. Chem. Soc., 115 (1993) N 23, S 10695-10704

  摘要：

  DOI：

文献信息

• Use of low molecular weight acetal, alcohol, acylated alcohol and ester compounds to block or reduce odor of carboxylic acids
  申请人：Senomyx, Inc.

  公开号：US20030089885A1

  公开（公告）日：2003-05-15

  Low molecular weight acetal, alcohol, O-acylated alcohol and ester compounds are identified that block the odor of specific carboxylic acids especially propionic acid, butyric acid, isovaleric acid 3-methyl-2-hexenoic acid and hexanoic acid. These compounds exhibit surprisingly high odor blocking properties and are therefore useful additives to compositions such as: a) personal care products including underarm deodorant and antiperspirant, hair shampoo and conditioner, toilet soap, and skin lotion; b) fabric care products including laundry detergents, fabric conditioners, and fabric fresheners; c) pet care products including deodorant, shampoo, conditioner, and d) home care products including air fresheners, carpet fresheners, surface cleaners and hand wash dish detergent.

  识别出低分子量的缩醛、醇、O-酰化醇和酯类化合物，可以阻止特定羧酸的气味，特别是丙酸、丁酸、异戊酸、3-甲基-2-己烯酸和己酸。这些化合物表现出惊人的高气味阻断性能，因此可作为以下配方的有用添加剂：a）个人护理产品，包括腋下除臭剂和止汗剂、洗发水和护发素、香皂和皮肤乳液；b）织物护理产品，包括洗衣液、织物柔顺剂和织物清新剂；c）宠物护理产品，包括除臭剂、洗发水、护发素；d）家居护理产品，包括空气清新剂、地毯清新剂、表面清洁剂和手洗碗清洁剂。
• Ishihara Kazuaki, Hanaki Naoyuki, Yamamoto Hisashi, J. Amer. Chem. Soc., 115 (1993) N 23, S 10695-10704
  作者：Ishihara Kazuaki, Hanaki Naoyuki, Yamamoto Hisashi

  DOI：——

  日期：——
• MUSAVIROV R. S.; KANTOR E. A.; RAXMANKULOV D. L., ZH. PRIKL. XIMII. 1976, 49, HO 11, 2513-2515
  作者：MUSAVIROV R. S.、 KANTOR E. A.、 RAXMANKULOV D. L.

  DOI：——

  日期：——
• [EN] USE OF LOW MOLECULAR WEIGHT ACETAL, ALCOHOL, ACYLATED ALCOHOL AND ESTER COMPOUNDS TO BLOCK OR REDUCE ODOR OF CARBOXYLIC ACIDS<br/>[FR] UTILISATION D'ACETAL A FAIBLE MASSE MOLECULAIRE, D'ALCOOL, D'ALCOOL D'ACYLE ET DE COMPOSES D'ESTERS AFIN DE BLOQUER OU REDUIRE L'ODEUR DES ACIDES CARBOXYLIQUES
  申请人：SENOMYX INC

  公开号：WO2002085294A2

  公开（公告）日：2002-10-31

  Low molecular weight acetal, alchol, O-acylated alcohol and ester compounds are identified that block the odor of specific carboylic acids especially propionic acid, butyric acid, isovaleric acid 3-methyl-2-hexenoic acid and hexanoic acid. These compounds exhibit surprisingly high odor blocking properties and are therefore useful additives to compositions such as: a) personal care products including underarm deodorant and antiperspirant, hair shampoo and conditioner, toilet soap, and skin lotion; b) fabric care products including laundry detergents, fabric conditioners, and fabric fresheners; c) pet care products including deodorant, shampoo, conditioner, and d) home care products including air fresheners, carpet fresheners, surface cleaners andhand wash dish detergent.