[Fe2(μ-OMe)2(1,4-di(2'-pyridyl)aminophthalazine)(OAc)4] | 782477-75-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: [Fe2(μ-OMe)2(1,4-di(2'-pyridyl)aminophthalazine)(OAc)4]
• 英文别名: 1-N,4-N-dipyridin-2-ylphthalazine-1,4-diamine;iron(3+);methanolate;tetraacetate
• CAS: 782477-75-2
• 化学式: C₂₈H₃₂Fe₂N₆O₁₀
• 分子量: 724.29
• InChiKey: YZUTWQBJYCHNEW-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 iron(II) acetate 、 1,4-di(2'-pyridyl)aminophthalazine 在 O₂ 作用下， 以 甲醇 为溶剂， 以62%的产率得到[Fe2(μ-OMe)2(1,4-di(2'-pyridyl)aminophthalazine)(OAc)4]
  参考文献：
  名称：

  Synthesis, structure and characterization of new complexes [Fe2(μ-OMe)2(PAP)(X)4] (PAP= 1,4-di(2′-pyridyl)aminophthalazine, X=Cl, OAc) and their oxidation catalysis

  摘要：

  Two dinuclear iron(III) complexes with tetradentate N-donor ligand 1,4-di(2'-pyridyl)aminophthalazine (PAP), [Fe-2(mu-OMe)(2)(PAP)Cl-4] (2) and [Fe-2(mu-OMe)(2)(PAP)(OAc)(4)] (3) were prepared and characterized. Single crystal X-ray molecular structure of [Fe-2(mu-OMe)(2)(PAP)Cl-4].2MeOH have been elucidated. The six-coordinate iron atoms are in distorted octahedral environment bridged by the oxygen atoms of two methoxy groups and the PAP ligand. The Mossbauer spectra of both complexes show one quadrupole doublet and the isomer shift and quadrupole splitting values indicate the presence of octahedral high-spin Fe-III ions. Complex 2 showed catalytic activity for alkane oxidation with hydrogen peroxide. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.05.012