N-(2-amino-5-diethylamino-phenethyl)-methanesulfonamide | 2359-50-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(2-amino-5-diethylamino-phenethyl)-methanesulfonamide
• 英文别名: N-(2-Amino-5-diaethylamino-phenaethyl)-methansulfonamid；N-[2-[2-amino-5-(diethylamino)phenyl]ethyl]methanesulfonamide
• CAS: 2359-50-4
• 化学式: C₁₃H₂₃N₃O₂S
• 分子量: 285.411
• InChiKey: RGQFFQXJSCXIJX-UHFFFAOYSA-N

物化性质

• 沸点：
  215-220 °C(Press: 1 Torr)
• 密度：
  1.179±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  19
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  83.8
• 氢给体数：
  2
• 氢受体数：
  5

文献信息

• One equivalent couplers and low pKa release dyes
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0574090A1

  公开（公告）日：1993-12-15

  A photographic element containing a dye which when released from a coupler has a sufficiently low pKa, generally less than about 5, such that the dye remains substantially or fully ionized during coating of the film and in the produced film, results in an element containing a dye which has the desired hue without the use of additional additives, such as mordants, to keep the dye ionized. The dye is also useful in photographic elements without release from a coupler, for example, as a filter dye.

  一种含有染料的摄影元素，当从偶联剂中释放出来时，该染料具有足够低的pKa，一般小于约5，因此在涂布膜和生产的膜中，染料保持大部分或完全电离，从而产生一种不需要使用额外添加剂（如媒染剂）来保持染料电离的所需色调的元素。该染料在摄影元素中也可用于不从偶联剂中释放的情况，例如作为滤色镜染料。
• Synthesis of peptoid substituted azole compounds
  申请人：——

  公开号：US20030187188A1

  公开（公告）日：2003-10-02

  Disclosed is a process for the preparation of a peptoid substituted azole compound comprising reacting an amino functionalized azole compound with a resin bound peptoid oligomer bearing a terminal halogen substituent followed by cleavage of the resultant product from the resin surface using a fluorinated organic acid in an inert solvent.

  本发明公开了一种制备肽样取代咪唑化合物的方法，包括将氨基功能化的咪唑化合物与带有端基卤素取代基的树脂结合的肽样寡聚体反应，随后在惰性溶剂中使用氟化有机酸从树脂表面解离所得产物。
• Light-sensitive silver halide color photographic material
  申请人：KONICA CORPORATION

  公开号：EP0087931A1

  公开（公告）日：1983-09-07

  Disclosed is a light-sensitive silver halide color photographic material, having a blue sensitive silver halide emulsion layer, a green sensitive silver halide emulsion and a red sensitive silver halide emulsion on a support; which comprises said red sensitive silver halide emulsion containing at least one kind of the compounds represented by the formula [I] shown below, and further the content of the silver halide contained in all of the aforesaid light-sensitive silver halide emulsion layer being 7.5 g/m2 or more as calculated on silver, and the content of the silver halide contained in said red sensitive silver halide emulsion being 3.5 g/m2 or more as calculated on silver: Formula [I]: wherein, X, R1 and R2 are as defined in the specification.

  本发明公开了一种感光型卤化银彩色感光材料，它具有蓝色感光型卤化银乳剂层、绿色感光型卤化银乳剂层和红色感光型卤化银乳剂层；其中，所述红色感光型卤化银乳剂层含有至少一种下式[I]所代表的化合物，并且上述所有感光型卤化银乳剂层所含卤化银的含量以银为单位计算为 7.5 g/m2 或以上，所述红色感光型卤化银乳剂层所含卤化银的含量以银为单位计算为 3.5 g/m2 或以上：式[I]：其中，X、R1 和 R2 如说明书中所定义。
• Silver halide photographic light-sensitive material
  申请人：KONICA CORPORATION

  公开号：EP0110633A2

  公开（公告）日：1984-06-13

  A silver halide photographic light-sensitive material is described which comprises a support having thereon a plurality of silver halide emulsion layers which possess different speeds but sensitivities in the same spectral region and at least one light-sensitive layer comprising a non-diffusible coupler capable of forming non-diffusible dye by reaction with an oxidation product of a color developing agent, wherein the silver halide emulsion layer having the highest speed among said plurality of silver halide emulsion layers contains a non-diffusible coupler capable of producing a movable dye by reaction thereof with an oxidation product of a color developing agent and a non-diffusible compound capable of releasing a development inhibitor by reaction thereof with an oxidation product of a color developing agent.

  描述了一种卤化银感光照相材料，它包括一个支架，支架上有多个卤化银乳剂层，这些乳剂层具有不同的速度，但在同一光谱区域具有不同的感光度，以及至少一个感光层，该感光层包含一个不可扩散耦合剂，该耦合剂能够通过与显色剂的氧化产物反应形成不可扩散染料、其中，在所述多个卤化银乳剂层中，速度最快的卤化银乳剂层包含一种非扩散耦合剂，该耦合剂能够通过与显色剂的氧化产物反应生成可移动染料，还包含一种非扩散化合物，该化合物能够通过与显色剂的氧化产物反应释放显影抑制剂。
• Silver halide photographic light-sensitive materials
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0295698A2

  公开（公告）日：1988-12-21

  There are provided by the invention silver halide photographic light-sensitive materials containing dyestuff(s) represented by the general formula (I): wherein R¹, R³, R⁴, R⁶, L₁, L₂, L₃, Z¹ and Z² are groups conventional in this technical field, and R² and R⁵ each represent an optionally substituted alkyl group, an optionally substituted aryl group, an optionally substituted heterocyclic group, COR⁷ or SO₂R⁷ (wherein R⁷ represents an optionally substituted alkyl group or an optionally substituted aryl group) (including the case where the dyestuff(s) is(are) in the form of salt(s)). The dyestuff(s) act(s) as a coloring agent for colored layer(s) for color filtering, antihalation, antiirradiation, etc. Silver halide photographic light-sensitive materials containing dyestuffs represented by the general formula (I) of the invention have remarkable effects, for example, that stability of dyestuffs in the membrane with time lapse is high, relative sensitivity is high, lowering of sensitivity in exposure to light under high humidity is small, image quality is excellent, there is only a little remaining color, and/or there is only a little fog, as compared with silver halide photographic light-sensitive materials containing conventional dyestuffs for the aforementioned purposes.

  本发明提供了含有通式(I)代表的染料的卤化银感光材料： 其中 R¹、R³、R⁴、R⁶、L₁、L₂、L₃、Z¹ 和 Z² 为本技术领域的常规基团，R² 和 R⁵ 分别代表任选取代的烷基、任选取代的芳基、任选取代的杂环基、COR⁷ 和 R⁸ 、任选取代的杂环基、COR⁷ 或 SO₂R⁷（其中 R⁷ 代表任选取代的烷基或任选取代的芳基）（包括染料以盐的形式存在的情况）。 染料可作为有色层的着色剂，用于滤色、防光、防辐射等。 含有本发明通式(I)所代表的染料的卤化银感光材料具有显著的效果，例如，与含有用于上述目的的传统染料的卤化银感光材料相比，染料在膜中随时间推移的稳定性高、相对感光度高、在高湿度下曝光时感光度降低小、图像质量优异、仅有少量残留色和/或仅有少量雾。