cis-dibenzothiazolyldibenzo-24-crown-8 | 1352090-53-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: cis-dibenzothiazolyldibenzo-24-crown-8
• 英文别名: 2-[31-(1,3-Benzothiazol-2-yl)-2,5,8,11,18,21,24,27-octaoxatricyclo[26.4.0.012,17]dotriaconta-1(28),12(17),13,15,29,31-hexaen-14-yl]-1,3-benzothiazole
• CAS: 1352090-53-9
• 化学式: C₃₈H₃₈N₂O₈S₂
• 分子量: 714.86
• InChiKey: UFDXLLQVFLSIBB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  50
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  156
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  4,4'-Diformyldibenzo-24-crown-8 、 2-氨基苯硫醇 以 乙醇 为溶剂， 反应 24.0h， 以47%的产率得到cis-dibenzothiazolyldibenzo-24-crown-8
  参考文献：
  名称：

  Synthesis and optical properties of cis-dibenzothiazolyldibenzo-24-crown-8

  摘要：

  AbstractNew crown ether carrying two fluorionophores of cis‐dibenzothiazolyldibenzo‐24‐crown‐8 was synthesized from cis‐diformyldibenzo‐24‐crown‐8 and 2‐aminobenzenethiol. The binding behavior and the optical properties of the crown ether were examined through UV‐visible spectroscopy and fluorescence spectroscopy. When complexed with Na+, K+, Rb+, and Cs+ ions, it led to intramolecular charge transfer and caused the changes of the fluorescence spectra. The protonation of the crown ether was also studied. With protonation using CF3COOH, the absorption bands and the fluorescence spectroscopy changed, the maximal fluorescence wavelengths red shifted and the fluorescence intensity with the maximum at 433 nm enhanced strongly. J. Heterocyclic Chem., (2011).

  DOI：

  10.1002/jhet.666

文献信息

• Synthesis and optical properties of cis-dibenzothiazolyldibenzo-24-crown-8
  作者：Dong-Jing Han、Zhi-Bin Huang、Shun-Jun Ji

  DOI：10.1002/jhet.666

  日期：2011.11

  AbstractNew crown ether carrying two fluorionophores of cis‐dibenzothiazolyldibenzo‐24‐crown‐8 was synthesized from cis‐diformyldibenzo‐24‐crown‐8 and 2‐aminobenzenethiol. The binding behavior and the optical properties of the crown ether were examined through UV‐visible spectroscopy and fluorescence spectroscopy. When complexed with Na+, K+, Rb+, and Cs+ ions, it led to intramolecular charge transfer and caused the changes of the fluorescence spectra. The protonation of the crown ether was also studied. With protonation using CF3COOH, the absorption bands and the fluorescence spectroscopy changed, the maximal fluorescence wavelengths red shifted and the fluorescence intensity with the maximum at 433 nm enhanced strongly. J. Heterocyclic Chem., (2011).