[Cu4(μ2,η1-S2CNPr2)4] | 52133-94-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Cu4(μ2,η1-S2CNPr2)4]
• CAS: 52133-94-5
• 化学式: C₂₈H₅₆Cu₄N₄S₈
• 分子量: 959.491
• InChiKey: MWKUYZCJFMIXQD-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  [Cu8(μ2,μ2-S2CNPr2)6][ClO4]2*2(chloroform) 以 氘代丙酮 为溶剂， 生成 [Cu(S2CNPr2)2][ClO4] 、 [Cu4(μ2,η1-S2CNPr2)4]
  参考文献：
  名称：

  A dithiocarbamate-stabilized copper(I) cube

  摘要：

  The disproportionation reaction between the copper(II) complexes, Cu(ClO(4))(2) center dot 6H(2)O and [Cu(S(2)CNR(2))(2)] is a well-established route to copper(III) Complexes [Cu(S(2)CNR(2))(2)][ClO(4)] but to date the nature of the copper(l) species generated has remained a mystery. We now show that with [Cu(S(2)CNPr(2))(2)] this is the copper(l) cluster, [Cu(8)(mu(2), mu(2)-S(2)CNPr(2))(6)][ClO(4)](2) which contains a cubic array of copper atoms, each face cube being capped by a dithiocarbarnate ligand such that the sulfur atoms define an icosahedron and the backbone carbons an octahedron around the cube centroid. A crystal structure of [Cu(4)(mu(2),eta (1)-S(2)CNBu(2))(4)] is also presented for comparison. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.08.034