2-[(2-propenyloxy)methyl]naphthalene | 93359-79-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-[(2-propenyloxy)methyl]naphthalene
• 英文别名: 2-(Prop-2-enoxymethyl)naphthalene
• CAS: 93359-79-6
• 化学式: C₁₄H₁₄O
• 分子量: 198.265
• InChiKey: DTBHYKNJBNXGAL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  叔丁基二甲基烯丙基硅醚 、 2-萘甲醛 在 三乙基硅烷 、 bismuth(III) bromide 作用下， 以 乙腈 为溶剂， 反应 0.17h， 以92%的产率得到2-[(2-propenyloxy)methyl]naphthalene
  参考文献：
  名称：

  In-situ generation of Et3SiBr from BiBr3 and Et3SiH and its use in preparation of dialkyl ethers

  摘要：

  The reported BiBr3-Et3SiH catalyzed reductive etherifications of silyl ethers with carbonyl compounds are shown to be catalyzed by the in situ formed Et3SiBr and verified by an independent use of the commercial reagent. As Et3SiBr is moisture sensitive and is not readily available, this in situ generation is still recommended as the method of choice. Utilizing this method, several alcohols were transformed under very mild conditions into dialkyl ethers via their silyl intermediates, such as TES, TBDMS, and TIPS. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(02)01532-0

文献信息

• NOXIOUS ARTHROPOD CONTROL AGENT CONTAINING AMIDE COMPOUND
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20170215424A1

  公开（公告）日：2017-08-03

  An object of the present invention is to provide a compound having the controlling activity on a noxious arthropod, and a noxious arthropod controlling agent containing an amide compound of formula (I): wherein X represents a nitrogen atom or a CH group, p represents 0 or 1, A represents a tetrahydrofuranyl group or the like, R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 7 represent a hydrogen atom or the like, n represents 1 or 2, Y represents an oxygen atom or the like, m represents any integer of 0 to 7, and Q represents a C1-8 chain hydrocarbon group optionally having a phenyl group or the like, has the excellent noxious arthropod controlling effect.

  本发明的一个目的是提供一种具有对有害节肢动物的控制活性的化合物，以及含有式（I）的酰胺化合物的有害节肢动物控制剂： 其中X代表氮原子或CH基团，p代表0或1，A代表四氢呋喃基团或类似物，R1、R2、R3、R4、R5、R6和R7代表氢原子或类似物，n代表1或2， Y代表氧原子或类似物，m代表0到7的任意整数，Q代表C1-8链烃基，可选地具有苯基或类似物，具有优异的有害节肢动物控制效果。
• US9854803B2
  申请人：——

  公开号：US9854803B2

  公开（公告）日：2018-01-02
• US9896535B2
  申请人：——

  公开号：US9896535B2

  公开（公告）日：2018-02-20