5-{8-(t-butoxycarbonylaminomethyl)-1,12-dimethylbenzo[c]phenanthrene-5-yl}methylaminomethyl-8-cyano-1,12-dimethylbenzo[c]phenanthrene | 473276-98-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 5-{8-(t-butoxycarbonylaminomethyl)-1,12-dimethylbenzo[c]phenanthrene-5-yl}methylaminomethyl-8-cyano-1,12-dimethylbenzo[c]phenanthrene
• 英文别名: (P,P)-5-{8-(t-butoxycarbonylaminomethyl)-1,12-dimethylbenzo[c]phenanthrene-5-yl}methylaminomethyl-8-cyano-1,12-dimethylbenzo[c]phenanthrene；(M,M)-5-{8-(t-butoxycarbonylaminomethyl)-1,12-dimethylbenzo[c]phenanthrene-5-yl}methylaminomethyl-8-cyano-1,12-dimethylbenzo[c]phenanthrene
• CAS: 473276-98-1
• 化学式: C₄₉H₄₅N₃O₂
• 分子量: 707.915
• InChiKey: DOOADQNJVHPZOY-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  5-{8-(t-butoxycarbonylaminomethyl)-1,12-dimethylbenzo[c]phenanthrene-5-yl}methylaminomethyl-8-cyano-1,12-dimethylbenzo[c]phenanthrene 在 lithium perchlorate 、 二异丁基氢化铝 、 三氟乙酸 作用下， 以 甲醇 、 正己烷 、 二氯甲烷 为溶剂， 反应 2.5h， 生成 5-{8-(aminomethyl)-1,12-dimethylbenzo[c]phenanthrene-5-yl}methylaminomethyl-8-aminomethyl-1,12-dimethylbenzo[c]phenanthrene triperchlorate
  参考文献：
  名称：

  Folding of dihelicenetriamines in water

  摘要：

  Diastereomeric triamines containing two helicene moieties, 1,12-dimethylbenzo[c]phenanthrene, were synthesized and found to form folded structures in the water. Such folding was not observed for an achiral compound possessing a naphthalene moiety. The (M,M)-dihelicenetriamine with matching configuration at the helicene moieties formed a more stable folded structure than the (P,M)-isomer containing two enantiomeric helicene groups. The most stable folded conformation was predicted by the Monte Carlo method with Amber force field of the dihelicenetriamine. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(02)00249-5
• 作为产物：
  描述：

  二碳酸二叔丁酯 在 palladium on activated charcoal sodium hydroxide 、 氢气 作用下， 以 甲醇 、 二氯甲烷 、 水 、 乙酸乙酯 、 甲苯 为溶剂， 反应 26.17h， 生成 5-{8-(t-butoxycarbonylaminomethyl)-1,12-dimethylbenzo[c]phenanthrene-5-yl}methylaminomethyl-8-cyano-1,12-dimethylbenzo[c]phenanthrene
  参考文献：
  名称：

  Folding of dihelicenetriamines in water

  摘要：

  Diastereomeric triamines containing two helicene moieties, 1,12-dimethylbenzo[c]phenanthrene, were synthesized and found to form folded structures in the water. Such folding was not observed for an achiral compound possessing a naphthalene moiety. The (M,M)-dihelicenetriamine with matching configuration at the helicene moieties formed a more stable folded structure than the (P,M)-isomer containing two enantiomeric helicene groups. The most stable folded conformation was predicted by the Monte Carlo method with Amber force field of the dihelicenetriamine. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(02)00249-5