<8-(dimethylaminomethyl)-1-naphthyl>phenylsilathione | 121543-30-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: <8-(dimethylaminomethyl)-1-naphthyl>phenylsilathione
• 英文别名: 8-(dimethylamino)methyl-1-naphthyl phenylsilanethione；[8-(dimethylaminomethyl)-1-naphthyl]phenylsilathione；8-(Dimethylamino)methyl-1-naphthyl phenyl silanethione；N,N-dimethyl-1-[8-[phenyl(sulfanylidene)silyl]naphthalen-1-yl]methanamine
• CAS: 121543-30-4
• 化学式: C₁₉H₁₉NSSi
• 分子量: 321.518
• InChiKey: HGXNWUXMTLUVRL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.16
• 拓扑面积：
  35.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  <8-(dimethylaminomethyl)-1-naphthyl>phenylsilathione 以 氘代吡啶 为溶剂， 反应 0.16h， 生成
  参考文献：
  名称：

  Reaction of 8-(dimethylamino)methyl-1-naphthyl phenyl silanethione with phosphorus ylides

  摘要：

  The title silanethione reacts with phosphorus ylides under conditions of kinetic control to give betaines containing a linear[GRAPHICS]fragment. Under conditions of thermodynamic control, the derivatives of phosphonium 1-silaacenaphthene-1-thiolate are formed.

  DOI：

  10.1007/bf00698899
• 作为产物：
  描述：

  N,N'-dimethyl<(8-dimethylaminomethyl)naphthyl>phenylsila-2-imidazoline 在 二硫化碳 作用下， 反应 0.08h， 生成 <8-(dimethylaminomethyl)-1-naphthyl>phenylsilathione
  参考文献：
  名称：

  Aminosilylation of heterocumulenes and the intramolecular decomposition of their silyl-functionalized adducts

  摘要：

  Heteroorganic amidosilanes are readily obtained by interaction of CO2, CS2 and other heterocumulenes with pentacoordinated diaminosilanes. A comparison is made with the corresponding reactions of tetracoordinated species. Decomposition of these bifunctional organosilanes gives 2-substituted ureido derivatives and base-stabilized low coordinated silicon species, seemingly by a unimolecular thermal beta-elimination.

  DOI：

  10.1016/0022-328x(91)86160-r