(5,10,15,20-tetra(4-cyanophenyl)porphyrinato)(2,4-pentanedionate)(methanol)ytterbium(III) | 1174219-80-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: (5,10,15,20-tetra(4-cyanophenyl)porphyrinato)(2,4-pentanedionate)(methanol)ytterbium(III)
• CAS: 1174219-80-7
• 化学式: C₅₄H₃₅N₈O₃Yb
• 分子量: 1016.96
• InChiKey: ZSTFUOFSCURGHX-KDTBAHQYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 水 、 5,10,15,20-tetrakis(4-cyanophenyl)porphirin 、 hydrated tris(2,4-pentanedionato) Yb(III) salt 以 further solvent(s) 为溶剂， 以65%的产率得到(5,10,15,20-tetra(4-cyanophenyl)porphyrinato)(2,4-pentanedionate)(methanol)ytterbium(III)
  参考文献：
  名称：

  Crystallography and photoluminescence properties of β-diketonate monoporphyrinate ytterbium(III) complexes

  摘要：

  The structures of two beta-diketonate monoporphyrinate ytterbium(III) complexes were characterized by single-crystal X-ray diffraction analysis revealing, for the first time, seven-coordinate Yb(III) metal centers. The results reveal that there is only one solvent molecule (water or methanol) coordinating to ytterbium(III) in the complexes. Their photoluminescence of complexes in solution also shows that water and methanol that bind to ytterbium(III) ion quench the near-infrared emission of lanthanide, resulting a shorter lifetime (similar to 2.4 mu s). Published by Elsevier B.V.

  DOI：

  10.1016/j.inoche.2008.05.028