tris(1,1,1,5,5,5-hexafluoroacetylacetonato)(tripyridin-2ylamine) thulium | 1225026-45-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris(1,1,1,5,5,5-hexafluoroacetylacetonato)(tripyridin-2ylamine) thulium
• CAS: 1225026-45-8
• 化学式: C₃₀H₁₅F₁₈N₄O₆Tm
• 分子量: 1038.38
• InChiKey: CYYZDNDOSYSEQN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  tri-(2-pyridyl)amine 、 tris(1,1,1,5,5,5-hexafluoroacetylacetonato) thulium*2H2O 以 乙醇 为溶剂， 以35.19%的产率得到tris(1,1,1,5,5,5-hexafluoroacetylacetonato)(tripyridin-2ylamine) thulium
  参考文献：
  名称：

  Synthesis and photoluminescence properties of heteroleptic Eu3+, Tb3+ and Tm3+ complexes

  摘要：

  Five Eu(III), four Tb(III) and two Tm(III) multichromophoric complexes (1-Eu, 1-Th, 2-Eu, 3-Eu, 3-Th, 3-Tm. 4-7b, 4-Tm, 5-Eu. 6-Eu and 6-Th: where 1 = tris[dibenzoylmethanido] (4'-chloro-2,2'-6',2 ''-terpyndine), 2 = tris[dibenzoylmethanido] (4'-(9H-carbazol-9yl)-2.2':6'.2 ''-terpyridine), 3 = tris(1.1,1.5.5.5-hexafluoroacetylacetonato), 4 = tris[1,1,5,5,5-hexafluoroacetylacetonato] (tripyridin-2-ylamine), 5 = tris[dibenzoylmethanido][N-(4-(9H-carbazol-9-yl)butyl)-N-(dipyridin-2-yl)amine] and 6 = tris[dibenzoylmethanido][N-(6-(9H-carbazol-9-yl)hexyl)-N-(dipyridin-2-yl)amine]) emitting in the blue (Tm), green (Tb) and red (Eu) spectral regions, have been synthesized and characterized. The complexes involve five different coordinating (2.2':6'.2 ''-terpyridine (terpy): dibenzoylmethane (dbm); 1,1,1,5,5,5-hexafluoroacetylacetonato (hfa), tripyridin-2-ylamine (tri-amine) and N-(dipyridin-2-yl)amine (di-amine)) and one non-coordinating (carbazole) units. The synthesis and photophysical properties of these complexes are reported addressing the influence of the various ligands on the lanthanide metal-centered luminescence in CH2Cl2 solution and solid state matrices. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2009.06.096