| 474976-64-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并硫氮卓类
• CAS: 474976-64-2
• 化学式: C₆₀H₆₆N₁₂NiO₈S₄
• 分子量: 1270.21
• InChiKey: RUXWNNKMMXGAEE-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  、 trifluoroborane diethyl ether 以 乙腈 为溶剂， 以47%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of new (E,E)-dioxime and its homo and heterotrinuclear complexes containing dioxadithiadiazamacrobicycle moiety

  摘要：

  The new quinoxaline substituted (E,E)-dioxime (H2L) containing a dioxadithiadiazamacrobicycle has been synthesized from a 2,3-phenylenediamine attached mixed-donor-macrobicycle unit and cyanogen-di-N-oxide. The mononuclear Ni(II), BF2+-capped Ni(II) and heterotrinuclear Cu(I)Ni(II)Cu(I) complexes were prepared and their structures were confirmed elemental analysis, H-1, C-13 NMR, IR and FAB MS spectral data. (C) 2002 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(02)01022-7
• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 N-[10-(hydroxyamino)-4,15-dioxa-26,36-dithia-1,8,11,18-tetrazahexacyclo[16.10.10.05,14.07,12.020,25.030,35]octatriaconta-5(14),6,8,10,12,20,22,24,30,32,34-undecaen-9-yl]hydroxylamine 在 三乙胺 作用下， 以 乙醇 为溶剂， 以86%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of new (E,E)-dioxime and its homo and heterotrinuclear complexes containing dioxadithiadiazamacrobicycle moiety

  摘要：

  The new quinoxaline substituted (E,E)-dioxime (H2L) containing a dioxadithiadiazamacrobicycle has been synthesized from a 2,3-phenylenediamine attached mixed-donor-macrobicycle unit and cyanogen-di-N-oxide. The mononuclear Ni(II), BF2+-capped Ni(II) and heterotrinuclear Cu(I)Ni(II)Cu(I) complexes were prepared and their structures were confirmed elemental analysis, H-1, C-13 NMR, IR and FAB MS spectral data. (C) 2002 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(02)01022-7