N-trimethylsilylethanesulfonimidoyl Chloride | 138937-45-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: N-trimethylsilylethanesulfonimidoyl Chloride
• 英文别名: [(chloro-ethyl-oxo-λ6-sulfanylidene)amino]-trimethylsilane
• CAS: 138937-45-8
• 化学式: C₅H₁₄ClNOSSi
• 分子量: 199.777
• InChiKey: WURJVPHWWPNNCE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.46
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  37.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-trimethylsilylethanesulfonimidoyl Chloride 、 苯酚 在 三乙胺 作用下， 以 苯 为溶剂， 以31%的产率得到Phenyl-N-trimethylsilyl Ethanesulfonimidate
  参考文献：
  名称：

  Roy, Aroop K., Journal of the American Chemical Society, 1993, vol. 115, # 7, p. 2598 - 2601

  摘要：

  DOI：
• 作为产物：
  描述：

  N-(三甲基硅烷基)乙烷磺酰胺 在 chlorotriphenylphosphonium chloride 、 三乙胺 作用下， 以 氯仿 为溶剂， 生成 N-trimethylsilylethanesulfonimidoyl Chloride
  参考文献：
  名称：

  Roy, Aroop K., Journal of the American Chemical Society, 1993, vol. 115, # 7, p. 2598 - 2601

  摘要：

  DOI：

文献信息

• Polyorganooxothiazenes and method for preparing same
  申请人：Dow Corning Corporation

  公开号：US05194557A1

  公开（公告）日：1993-03-16

  This invention provides polyorganooxothiazenes exhibiting levels of molecular weight and properties not heretofore achieved by similar polymers reported in the prior art. The sulfonimidates that are condensed to form the polymers are prepared using a novel reaction between an N-triorganosilylsulfonamide and a triorganodihalophosphorane to form the corresponding N-triorganosilylsulfonimidoyl halide that is subsequently reacted with a fluorinated alcohol or phenol to form the N-triorgano-silylsulfonimidate.

  本发明提供了聚有机氧硫氮烯，其分子量和性能水平在先前报道的类似聚合物中尚未达到。用于形成聚合物的磺酰亚胺酯是通过一种新颖的反应制备的，该反应在N-三有机硅基磺酰胺和三有机卤代膦之间进行，形成相应的N-三有机硅基磺酰亚胺酰卤，随后与氟化醇或酚反应形成N-三有机硅基磺酰亚胺酯。
• Method for preparing sulfonimidoyl halides
  申请人：Dow Corning Corporation

  公开号：US05068379A1

  公开（公告）日：1991-11-26

  N-triorganosilylsulfonimidoyl halides are prepared using a novel series of reactions from compounds of hexavalent sulfur selected from amides, chlorides and anhydrides of organosulfonic acids. More specifically, the present method relates to the reaction of an N-triorganosilyl- or an N,N-bis(triorganosilyl)-sulfonamide with a triorganodihalophosphorane to form the corresponding sulfonimidoyl halide.

  N-三有机基硫酰亚胺卤化物是使用一系列新颖的反应从六价硫化合物中制备而成，所选的六价硫化合物包括有机磺酸酰胺、氯化物和酸酐。更具体地说，本方法涉及将N-三有机基或N,N-双(三有机基)磺酰胺与三有机卤代膦反应，形成相应的磺酰亚胺卤化物。
• Roy Aroop K., J. Amer. Chem. Soc., 115 (1993) N 7, S 2598-2603
  作者：Roy Aroop K.

  DOI：——

  日期：——
• Synthesis, Characterization, and Theoretical Analysis of Soluble Poly(oxothiazenes): The Ambient Temperature Lewis Acid Catalyzed<i>in Situ</i>Polymerization of<i>N</i>-Silylsulfonimidoyl Chlorides
  作者：Victoria Aldeva、Sossina Gezahegn、Babak Panahi、Michelle Shuoprasad、Jon Ward、Daniel A. Foucher、Robert A. Gossage、Andrew R. McWilliams

  DOI：10.1021/ma302424u

  日期：2013.4.9

  The ambient temperature condensation, to yield low molecular weight poly(methyloxothiazene) (M-w = 1 x 10(4); PDI = 1.4), can be achieved by the reaction of MeS(O-2)NHSiMe3 and SOCl2-this latter reaction being performed in an attempt to isolate ClSMe(O)NSiMe3 (6a). The in situ addition of a Lewis acid initiator (e.g., PCl5) to freshly prepared samples of N-silylsulfonimidoyl chlorides (ClSR(O)NSiMe3, 6a-d, R = Me, Et, Ph, p-C6H4Me) yielded high molecular weight, narrowly dispersed polymers, 5a-d (M-w = 6.7 x 10(4)-3.3 x 10(6); PDI = 1.2-1.6) of general formula [RS(O)=N](n). These materials have been characterized by GPC, NMR (H-1, C-13) spectroscopy, and DSC. UV-vis spectroscopy of CH2Cl2 solutions of 5a-d reveal a high-energy pi-pi* transition (lambda(max) = 300-350 nin) that tails into the visible. Additionally, theoretical modeling of oligomeric (rnethyloxothiazenes) at either a semiempirical, Hartree-Fock, or DFT level of theory suggests that these polymers adopt an irregular helical architecture.
• Roy, Aroop K., Journal of the American Chemical Society, 1993, vol. 115, # 7, p. 2598 - 2601
  作者：Roy, Aroop K.

  DOI：——

  日期：——