trioctylmethylammonium bis(2,4,4-trimethylpentyl)dithiophosphinate | 945539-30-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: trioctylmethylammonium bis(2,4,4-trimethylpentyl)dithiophosphinate
• 英文别名: Trioctylmethylammonium di(2,4,4-trimethylpentyl)dithiophosphinate；methyl(trioctyl)azanium;sulfanylidene-sulfido-bis(2,4,4-trimethylpentyl)-λ5-phosphane
• CAS: 945539-30-0
• 化学式: C₁₆H₃₄PS₂*C₂₅H₅₄N
• 分子量: 690.262
• InChiKey: HERHZGWEEKYZED-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  14.59
• 重原子数：
  45
• 可旋转键数：
  29
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  33.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  dihydrogen tetrachloropalladate(II) 、 trioctylmethylammonium bis(2,4,4-trimethylpentyl)dithiophosphinate 以 盐酸 、 甲苯 为溶剂， 生成 [trioctylmethylammonium][Pd2Cl4(bis(2,4,4-trimethylpentyl)dithiophosphinate)]
  参考文献：
  名称：

  Palladium extraction by a cyanex 301-based binary extractant from chloride solutions

  摘要：

  We studied the extraction of chloropalladium complexes by solutions of trioctylmethylammonium di(2,4,4-trimethylpentyl)dithiophosphinate in toluene over a wide range of aqueous acidities. Distribution factors and spectroscopic studies of extraction products showed that (R4N)[Pd(2)Cl(4)A] complexes are formed in the organic phase during extraction under near-saturation conditions. As the concentration of the binary extractant or dialkyldithiophosphinic acid increases, palladium di(2,4,4-trimethylpentyl)dithiophosphinate is formed in the organic phase.

  DOI：

  10.1134/s0036023609090277