| 1043962-89-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 1043962-89-5
• 化学式: C₂₀H₁₅N₃O₂Pd
• 分子量: 435.778
• InChiKey: GWSBVBJGCORUQZ-ZMPWJNBFSA-L

反应信息

• 作为产物：
  描述：

  N-[2-(p-tolylazo)phenyl]salicylideneamine 以 乙醇 、 叔丁醇 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, structure and reactivity of azosalophen complexes of palladium

  摘要：

  The ligands 2-(arylazo)-1-N-salicylidene phenylamine, H2Lsal, (where H represents the dissociable protons upon complexation) afford stable orthopalladated complexes, [(L-sal)Pd], upon treatment with Na-2[PdCl4]. The dinegative anionic (L-sal)(2-) ligands bind Pd(II) in a tetradentate (C, N, N, O) fashion with a distorted square planar geometry. The newly synthesized palladium complexes underwent oxygen insertion into the Pd-C bond with mCPBA (m-chloroperbenzoic acid) or TBHP (terbutylhydroperoxide)/[VO(acac)(2)] leading to the formation of stable azosalophen complexes of Pd(II) with the (O, N, N, O) coordination mode of the oxygenated ligand. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.03.028