3,7-diaza-5,5-dimethyl-2,8-bis(2'-hydroxyphenyl)nonane | 187960-80-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 3,7-diaza-5,5-dimethyl-2,8-bis(2'-hydroxyphenyl)nonane
• 英文别名: 2-[1-[[3-[1-(2-Hydroxyphenyl)ethylamino]-2,2-dimethylpropyl]amino]ethyl]phenol；2-[1-[[3-[1-(2-hydroxyphenyl)ethylamino]-2,2-dimethylpropyl]amino]ethyl]phenol
• CAS: 187960-80-1
• 化学式: C₂₁H₃₀N₂O₂
• 分子量: 342.481
• InChiKey: CNCIYJSRIXQHTG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  25
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  64.5
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  copper(II) choride dihydrate 、 3,7-diaza-5,5-dimethyl-2,8-bis(2'-hydroxyphenyl)nonane 、 sodium acetate 以 乙醇 为溶剂， 以79%的产率得到
  参考文献：
  名称：

  Synthesis and crystal structure of a novel trinuclear copper(II) complex from amine-phenol ligand

  摘要：

  The trinuclear copper(II) complex [Cu(3)L(2)(OAc)(2)] (where L = 3,7-diaza-5,5-dimethyl-2,8-bis(2'-hydroxyphenyl)nonane was prepared and characterized by UV-Vis, IR and ESR spectral studies, elemental analysis and single crystal X-ray diffraction analysis. The structure determination shows that the copper atoms are arranged in a linear fashion and the coordination geometry around each copper atom is square pyramidal. The Cu ... Cu distances are 2.969(1) and 2.942(1) Angstrom. The crystal is orthorhombic with space group Pbca, a = 18.478(2), b = 22.422(1), c = 27.008(10) Angstrom and Z = 8. The structure was refined to final R(f) = 0.060 for 4641 reflections with I> 1.8 sigma(I).

  DOI：

  10.1016/s0020-1693(96)05177-8
• 作为产物：
  描述：

  2,2'-[(2,2-dimethyl-1,3-propanediyl)bis(nitriloethylidyne)]bis[phenol] 在 sodium tetrahydroborate 作用下， 生成 3,7-diaza-5,5-dimethyl-2,8-bis(2'-hydroxyphenyl)nonane
  参考文献：
  名称：

  利用四齿 N2O2 供体还原席夫碱配体的羧酸桥三核混合价钴 (III/II/III) 配合物制备肖特基势垒二极管

  摘要：

  三种混合价三核钴( III )–钴( II )–钴( III )配合物，[Co II {(μ-L 1 )(μ-OAc)Co III (OAc)} 2 ]·2.67H 2 O ( 1 )、[Co II {(μ-L 1 )(μ-OOCPh)Co III (DMSO) 0.8 (OOCPh) 0.2 } 2 ](ClO 4 ) 1.6 ( 2 ) 和 [Co II {(μ-L 2 ) (μ-OOCPh)Co III (DMSO) 0.75 (OOCPh) 0.25 }2 ](ClO 4 ) 1.5 ( 3 )，使用两个四齿 N 2 O 2供体“还原席夫碱”配体 H 2 L 1 {1,3-双(2-羟基苄氨基)2,2-二甲基丙烷}和H 2 L 2 {2,2'-[1,1'-(丙烷-2,2-二亚氨基)二亚乙基]联苯酚}，以及乙酸盐或苯甲酸盐作为阴离子共配体。这些配合物已通过光谱测量进行了表征，并通过单晶

  DOI：

  10.1039/d3nj01829f

文献信息

• Investigation on the thermal decomposition some heterodinuclear NiII-MII complexes prepared from ONNO type reduced Schiff base compounds (M II=ZnII, CdII)
  作者：M. Aksu、S. Durmuş、M. Sari、K. C. Emregül、I. Svoboda、H. Fuess、O. Atakol

  DOI：10.1007/s10973-006-7729-5

  日期：2007.11

  N,N′-bis(salicylidene)-1,3-propanediamine (LH2), N,N′-bis(salicylidene)-2,2′-dimethyl-1,3-propanediamine (LDMH2), N,N′-bis(salicylidene)-2-hydroxy-1,3-propanediamine (LOH3), N,N′-bis(2-hydroxyacetophenylidene)-1,3-propanediamine (LACH2) and N,N′-bis(2-hydroxyacetophenone)-2,2′-dimethyl-1,3-propanediamine (LACDMH2) were synthesized and reduced to their phenol-amine form in alcoholic media using NaBH4

  N，N'-双（水杨亚基）-1,3-丙二胺（LH 2），N，N'-双（水杨亚基）-2,2'-二甲基-1,3-丙二胺（LDMH 2），N，N ′-双（水杨亚基）-2-羟基-1,3-丙二胺（LOH 3），N，N'-双（2-羟基乙酰亚苯基）-1,3-丙二胺（LACH 2）和N，N'-bis（合成了2-羟基苯乙酮）-2,2'-二甲基-1,3-丙二胺（LACDMH 2），并使用NaBH 4（L H H 2，LDM H H 2，LOH H）在酒精介质中还原成酚胺形式。H 2，LAC H H 2和LACDM H H2）。根据DMF介质中的模板方法，使用Ni（II），Zn（II）和Cd（II）盐合成异核复合物。
• Synthesis and crystal structure of a novel trinuclear copper(II) complex from amine-phenol ligand
  作者：S. Kannan、M.R.A. Pillai、P.A. Droege、S. Jurisson、C.L. Barnes

  DOI：10.1016/s0020-1693(96)05177-8

  日期：1997.1

  The trinuclear copper(II) complex [Cu(3)L(2)(OAc)(2)] (where L = 3,7-diaza-5,5-dimethyl-2,8-bis(2'-hydroxyphenyl)nonane was prepared and characterized by UV-Vis, IR and ESR spectral studies, elemental analysis and single crystal X-ray diffraction analysis. The structure determination shows that the copper atoms are arranged in a linear fashion and the coordination geometry around each copper atom is square pyramidal. The Cu ... Cu distances are 2.969(1) and 2.942(1) Angstrom. The crystal is orthorhombic with space group Pbca, a = 18.478(2), b = 22.422(1), c = 27.008(10) Angstrom and Z = 8. The structure was refined to final R(f) = 0.060 for 4641 reflections with I> 1.8 sigma(I).
• Fabrication of Schottky barrier diodes utilizing carboxylate bridged trinuclear mixed valence cobalt(<scp>iii</scp>/<scp>ii</scp>/<scp>iii</scp>) complexes of tetradentate N₂O₂donor reduced Schiff base ligands
  作者：Sudip Bhunia、Pubali Das、Snehasis Banerjee、Rosa M. Gomila、Michael G. B. Drew、Antonio Frontera、Partha Pratim Ray、Shouvik Chattopadhyay

  DOI：10.1039/d3nj01829f

  日期：——

  67H2O (1), [CoII(μ-L1)(μ-OOCPh)CoIII(DMSO)0.8(OOCPh)0.2}2](ClO4)1.6 (2) and [CoII(μ-L2)(μ-OOCPh)CoIII(DMSO)0.75(OOCPh)0.25}2](ClO4)1.5 (3), have been synthesized using two tetradentate N2O2 donor ‘reduced Schiff base’ ligands, H2L1 1,3-bis(2-hydroxybenzylamino)2,2-dimethylpropane} and H2L2 2,2′-[1,1′-(propane-2,2-diyldiimino)diethylidene]diphenol}, and acetate or benzoate as anionic co-ligands.

  三种混合价三核钴( III )–钴( II )–钴( III )配合物，[Co II (μ-L 1 )(μ-OAc)Co III (OAc)} 2 ]·2.67H 2 O ( 1 )、[Co II (μ-L 1 )(μ-OOCPh)Co III (DMSO) 0.8 (OOCPh) 0.2 } 2 ](ClO 4 ) 1.6 ( 2 ) 和 [Co II (μ-L 2 ) (μ-OOCPh)Co III (DMSO) 0.75 (OOCPh) 0.25 }2 ](ClO 4 ) 1.5 ( 3 )，使用两个四齿 N 2 O 2供体“还原席夫碱”配体 H 2 L 1 1,3-双(2-羟基苄氨基)2,2-二甲基丙烷}和H 2 L 2 2,2'-[1,1'-(丙烷-2,2-二亚氨基)二亚乙基]联苯酚}，以及乙酸盐或苯甲酸盐作为阴离子共配体。这些配合物已通过光谱测量进行了表征，并通过单晶