3-phenyl-2,3-dihydrobenzo[h][1,4]benzodioxine | 121687-96-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并二恶烷
• 英文名称: 3-phenyl-2,3-dihydrobenzo[h][1,4]benzodioxine
• CAS: 121687-96-5
• 化学式: C₁₈H₁₄O₂
• 分子量: 262.308
• InChiKey: VCCSADLEYKWDLF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.35
• 重原子数：
  20.0
• 可旋转键数：
  1.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  18.46
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  1,2-萘醌 、 苯乙烯 生成 3-phenyl-2,3-dihydrobenzo[h][1,4]benzodioxine
  参考文献：
  名称：

  TAKUWA, AKIO, CHEM. LETT.,(1989) N, C. 5-8

  摘要：

  DOI：

文献信息

• An Evidence for Remarkable Difference of the Electrophilicity between Two Carbonyl Groups in the Photoexcited 1,2-Naphthoquinone. Photocycloaddition Reaction of 1,2-Naphthoquinone with Olefins
  作者：Akio Takuwa

  DOI：10.1246/cl.1989.5

  日期：1989.1

  The [4+2]photocycloaddition reactions between 1,2-naphthoquinone and olefins have been investigated. From the results of the stereochemistry and the regiochemistry of the adducts, it is concluded that the carbonyl oxygen atom at the position 2 in the photoexcited triplet state of 1,2-naphthoquinone attacks selectively one of the olefinic carbons.

  研究了 1,2-萘醌与烯烃之间的 [4+2] 光环加成反应。从加合物的立体化学和区域化学的结果可以得出结论，1,2-萘醌的光激发三重态中位置 2 的羰基氧原子选择性地攻击烯烃碳之一。
• Cu₂O-Catalyzed Tandem Ring-Opening/Coupling Cyclization Process for the Synthesis of 2,3-Dihydro-1,4-benzodioxins
  作者：Weiliang Bao、Yunyun Liu、Xin Lv、Weixing Qian

  DOI：10.1021/ol801444p

  日期：2008.9.1

  2, 3-Dihydro-1,4-benzodioxins can be prepared in a tandem one-pot procedure by reaction of o-iodophenols with epoxides catalyzed by Cu2O/1,10-phenanthroline/Cs2CO3 system. The reaction is suggested to occur via a novel ring-opening/coupling mechanism, giving moderate to good yields. Moreover, both aryl and aliphatic epoxides are tolerated under these conditions.