1-((E)-1-(4-nitrophenyl)prop-1-en-2-yl)benzene | 59344-63-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1-((E)-1-(4-nitrophenyl)prop-1-en-2-yl)benzene
• 英文别名: 1c-(4-nitro-phenyl)-2-phenyl-propene；1c-(4-Nitro-phenyl)-2-phenyl-propen；1-Nitro-4-[(1E)-2-phenyl-1-propen-1-yl]benzene；1-nitro-4-[(E)-2-phenylprop-1-enyl]benzene
• CAS: 59344-63-7
• 化学式: C₁₅H₁₃NO₂
• 分子量: 239.274
• InChiKey: DOGXCJRUBXAKSF-VAWYXSNFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.16
• 重原子数：
  18.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  43.14
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  、 氢化铝锂 生成 1-((E)-1-(4-nitrophenyl)prop-1-en-2-yl)benzene
  参考文献：
  名称：

  HUGGINS J. M.; BERGMAN R. G., J. AMER. CHEM. SOC., 1981, 103, NO 11, 3002-3011

  摘要：

  DOI：

文献信息

• A simple, phosphine free, reusable Pd(<scp>ii</scp>)–2,2′-dihydroxybenzophenone–SBA-15 catalyst for arylation and hydrogenation reactions of alkenes
  作者：Anish Lazar、Chathakudath P. Vinod、Anand Pal Singh

  DOI：10.1039/c5nj02686e

  日期：——

  complexation with Pd(II)Cl2 to get Pd(II)–DHBP@SBA-15. The synthesized catalysts were characterized by elemental analysis, XRD, N2 sorption analyses, TG, DTA, FT-IR, solid state 13C and 29Si NMR spectra, XPS, UV-Visible, SEM, EDAX and TEM. The synthesized catalysts were screened in arylation (Heck reactions) and hydrogenation reactions of alkenes, and the results show that Pd(II)–DHBP@SBA-15 exhibits

  通过后接枝方法，开发并报道了一种高效，简单，无膦和助催化剂的C-C偶联反应非均相催化剂。共价锚定膦不含钯（II型）的2,2'-二羟基二苯酮（DHBP）络合物在有机官能化SBA-15已由之间的反应合成的氨基官能化的SBA-15（NH 2 SBA-15）和2,2'-二羟基二苯甲酮（DHBP）配体，并与Pd（II）Cl 2进一步络合，得到Pd（II）–DHBP @ SBA-15。通过元素分析，XRD，N 2吸附分析，TG，DTA，FT-IR，固态13 C和29表征了合成的催化剂Si NMR光谱，XPS，紫外可见光，SEM，EDAX和TEM。在烯烃的芳基化反应（Heck反应）和加氢反应中筛选了合成的催化剂，结果表明，Pd（II）-DHBP @ SBA-15对烯烃的芳基化和氢化反应具有很高的转化率和选择性。锚固的固体催化剂可以有效地回收利用并重复使用几次，而不会造成活性的重大损失。
• L'Ecuyer; Olivier, Canadian Journal of Research, Section B: Chemical Sciences, 1950, vol. 28, p. 648,650
  作者：L'Ecuyer、Olivier

  DOI：——

  日期：——
• Biopolymer-metal complex wool–Pd as a highly active heterogeneous catalyst for Heck reaction in aqueous media
  作者：Shang Wu、Hengchang Ma、Xiaojie Jia、Yunmei Zhong、Ziqiang Lei

  DOI：10.1016/j.tet.2010.10.062

  日期：2011.1

  Heterogeneous palladium catalysts, a biopolymer complex wool-Pd, have been applied in water-mediated coupling reactions of aryl bromides without assistance of any phosphine ligands. The catalyst was characterized by XPS, ICP. The results showed that aryl bromides could carry out the coupling reaction with a variety of alkenes at 80 degrees C, in aqueous media under atmospheric condition. More importantly, the cheap catalyst is stable, which shows negligible metal leaching, and retain good activity for at least ten successive runs without any additional activation treatment. This approach would be very useful from a practical viewpoint. (C) 2010 Elsevier Ltd. All rights reserved.
• Rasumowskii; Rytschkina, Zhurnal Obshchei Khimii, 1957, vol. 27, p. 3143,3145; engl. Ausg. S. 3181, 3183
  作者：Rasumowskii、Rytschkina

  DOI：——

  日期：——