[Co(1,4-bis(4-oxy-1,2-benzenedicarboxylic acid)benzene(-2H))(1,10-phenanthroline)₂(H₂O)] | 1477517-85-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [Co(1,4-bis(4-oxy-1,2-benzenedicarboxylic acid)benzene(-2H))(1,10-phenanthroline)₂(H₂O)]
• 英文别名: [Co(1,4-bis(4-oxy-1,2-benzenedicarboxylic acid)benzene(-2H))(phen)₂(H₂O)]
• CAS: 1477517-85-3
• 化学式: C₄₆H₃₀CoN₄O₁₁
• 分子量: 873.758
• InChiKey: UPYVIINWGSSOTP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 cobalt(II) nitrate hexahydrate 、 1,4-bis(4-oxy-1,2-benzenedicarboxylic acid)benzene 以 水 为溶剂， 反应 92.0h， 以57%的产率得到[Co(1,4-bis(4-oxy-1,2-benzenedicarboxylic acid)benzene(-2H))(1,10-phenanthroline)₂(H₂O)]
  参考文献：
  名称：

  Syntheses, crystal structures and properties of five divalent transition metal coordination compounds based on a semirigid tetracarboxylic acid ligand

  摘要：

  Five divalent transition metal coordination compounds based on a semirigid tetracarboxylic acid have been synthesized by the hydrothermal method, namely, [MnL(0.5)phen](n) (1), [CdL(0.5)phen](n) (2), [Co(H2L)(phen).2H(2)O] n (3), {[Ni2L(phen) 2(H2O) 6].2H(2)O} n (4) {[Zn2L(phen) 4(H2O) 2].2H(2)O}(n) (5) (H4L = 1,4-bis(4-oxy-1,2-benzene dicarboxylic acid) benzene, phen = 1,10-phenanthroline). These compounds were structurally characterized by infrared spectra, thermogravimetric analyses and single crystal X-ray diffractions. The isostructural 1 and 2 exhibit the two-dimensional layered structures. Compound 3 and 4-5 reveal a mononuclear and two dinuclear structures, respectively. In addition, the magnetic property of 1 and the photoluminescence of 2 and 5 were also investigated, respectively. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.08.022