{iron(II)tris-cyclohexanedione-1,2-dioxime}sulfate | 65967-93-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫酸及其衍生物
• 英文名称: {iron(II)tris-cyclohexanedione-1,2-dioxime}sulfate
• CAS: 65967-93-3
• 化学式: C₁₈H₃₀FeN₆O₆*O₄S
• 分子量: 578.383
• InChiKey: ZDNCIGFEUXYBBB-IKXJQUHTSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  {iron(II)tris-cyclohexanedione-1,2-dioxime}sulfate 、 四氯化锗 在 DMSO 作用下， 以 further solvent(s) 为溶剂， 以29%的产率得到{(H2)iron(II)tris-cyclohexanedione-1,2-dioximate(Ge2O3)*DMSO}n
  参考文献：
  名称：

  Macrobicyclic d-metal tris-dioximates obtained by cross-linking with p-block elements—V. Synthesis and properties of polymeric germanium-containing iron(II) dioximates

  摘要：

  Template condensation on the Fe2+ ion and exchange reactions of cross-linking groups were used to obtain macrobicyclic germanium-containing iron(II) tris-dioximates, which were isolated as polymeric compounds of the composition [H2FeD3(Ge2O3).x(solvent)]n. IR, UV-vis and (Fe-57) Mossbauer spectra have been obtained.The coordination polyhedron of iron(II) atoms has a trigonal antiprismatic geometry close to octahedral according to the Mossbauer spectroscopic data. The "macrocyclic" ligand field-force increase effect in germanium-containing complexes is close to that in boron-containing clathrochelates and is much more pronounced than in their tin-containing analogues.The polymeric structure was formed through the bridging oxygen atoms of the cross-linking groups.

  DOI：

  10.1016/s0277-5387(00)83202-7

文献信息

• Macrobicyclic d-metal tris-dioximates obtained by cross-linking with p-block elements. Part III. Template synthesis, structure and properties of clathrochelate tin-containing iron(II) dioximates formed by tin tetrachloride
  作者：Yan Z. Voloshin、Nina A. Kostromina、Alexander Y. Nazarenko、Ernest V. Polshin

  DOI：10.1016/s0020-1693(00)81680-1

  日期：1991.7

  aliphatic, aromatic and alicyclic dioximes containing tin(IV) tetrachloride on iron(II) ion results in the formation of anionic clathrochelate complexes, which have been isolated and characterized as salts with organic bases of the general compositions [FeD3(SnCl3)2](HAm)2, where D2− is a dioxime dianion and Am is a aliphatic or aromatic amine. The composition and clathrochelate nature of the complexes obtained

  摘要许多含四氯化锡（IV）的脂族，芳族和脂环族二肟在铁（II）离子上的模板缩合导致阴离子笼形螯合物的形成，该络合物已被分离并表征为与一般组成的有机碱形成的盐[FeD3（SnCl3）2]（HAm）2，其中D2-是二肟基二阴离子，Am是脂肪族或芳香族胺。通过IR，电子吸收，1H，13C 1H}，119Sn NMR和57Fe，119Sn Mossbauer光谱的元素分析结果证实了所得配合物的组成和笼形螯合物性质。根据57Fe Mossbauer光谱数据，该配合物具有配位多面体的三角反棱角几何形状，畸变角为40-55°。笼形螯合物含锡配合物的“大环”配体场力增加作用不如含硼大双环配合物。Mossbauer和119Sn NMR光谱的参数表明交联的含锡片段的高度对称的八面体几何形状。