[Cd(1,10-phenanthroline)(naphthalene-1,4,5,8-tetracarboxylic acid 4,5-anhydride(2-))(water)2]n | 868833-02-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [Cd(1,10-phenanthroline)(naphthalene-1,4,5,8-tetracarboxylic acid 4,5-anhydride(2-))(water)2]n
• CAS: 868833-02-7
• 化学式: C₂₆H₁₆CdN₂O₉
• 分子量: 612.831
• InChiKey: MVQRNGMPVLKTMW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 1,4,5,8-萘四甲酸酐 、 cadmium(II) acetate dihydrate 以 水 为溶剂， 以65%的产率得到[Cd(1,10-phenanthroline)(naphthalene-1,4,5,8-tetracarboxylic acid 4,5-anhydride(2-))(water)2]n
  参考文献：
  名称：

  Two photoluminescent coordination polymers based on naphthalene-1,4,5,8-tetracarboxylic acid 4,5-anhydride

  摘要：

  Two cadmium(II)-ntcaa coordination polymers, [Cd(phen)(ntcaa)(H2O)(2)](n) (1) and [Cd-2(4,4'-bpy)(ntcaa)(2)](n) (2) (ntcaa = naphthalene-1,4,5,8-tetracarboxylic acid 4,5-anhydride, phen = 1,10-phenanthroline, 4,4-bpy = 4,4'-bipyridine), were synthesized via hydrothermal method. The structure of compound 1 is a neutral comb-like chain with pi-pi interactions between the phen and naphthalene aromatic rings, while that of 2 possesses an interesting baluster structure composed of helix chain as post and 4,4'-bpy as connector. Photoluminescent investigations reveal that both compounds exhibit strong emissions in the solid state. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.04.010