trans-bis(acetato-O)bis(2-amino-6-methylpyridine-N)copper(II) | 234752-59-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: trans-bis(acetato-O)bis(2-amino-6-methylpyridine-N)copper(II)
• 英文别名: copper;6-methylpyridin-2-amine;diacetate
• CAS: 234752-59-1
• 化学式: C₁₆H₂₂CuN₄O₄
• 分子量: 397.921
• InChiKey: FFZOYBBROPOBRD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.55
• 重原子数：
  25
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  158
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2-氨基-6-甲基吡啶 、 tetrakis(acetato)diaquadicopper(II) 以 乙腈 为溶剂， 生成 trans-bis(acetato-O)bis(2-amino-6-methylpyridine-N)copper(II)
  参考文献：
  名称：

  trans-Bis(acetato-O)bis(2-amino-6-methylpyridine-N)copper(II)

  摘要：

  In the title compound, [Cu(C2H3O2)(2)(C6H8N2)(2)], the Cu atom is surrounded by two O atoms from the two monodentate acetate ligands and by two pyridine N atoms from the two 2-amino-6-methylpyridine ligands in a trans square-planar arrangement. The Cu-O and Cu-N distances are 1.952 (2) and 2.046 (2) Angstrom, respectively. The complex has an inversion centre. The remaining carboxylate O atoms are located at 2.764 (3) Angstrom from the Cu atom, above and below this plane. The coordination around the Cu atom can therefore be described as (4+2). The pyridine ring is twisted 73.2 (1)degrees with respect to the plane formed by the Cu, the N and the more strongly bonded O atoms.

  DOI：

  10.1107/s0108270199004345