copper(II) dimethylglyoximate | 5327-14-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: copper(II) dimethylglyoximate
• 英文别名: {Cu(dimethylglyoximate)2}；Cu(dmg)₂；butanedione dioxime ; copper (II)-compound；Cu(dimethylglyoximate(1-))2；[Cu(dimethylglyoxime-H)2]；Cu(Hdmg)2
• CAS: 5327-14-0
• 化学式: 2C₄H₇N₂O₂*Cu
• 分子量: 293.77
• InChiKey: SYGQQAZBKZVCLK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.79
• 重原子数：
  9.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  68.01
• 氢给体数：
  1.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  potassium iodide 、 copper(II) dimethylglyoximate 以 乙醇 为溶剂， 反应 8.0h， 生成 copper(I) iodide
  参考文献：
  名称：

  Application of nanoparticle mediated N-arylation of amines for the synthesis of pharmaceutical entities using vit-E analogues as amphiphiles in water

  摘要：

  首次在水中开发了以维生素E类似物为两性分子的CuI纳米颗粒催化的胺的分子内和分子间N-芳基化反应，并扩展到唑类化合物、取代吲哚、生物活性天然产物和药物实体的中间体。

  DOI：

  10.1039/c4ra15267k
• 作为产物：
  描述：

  二甲基乙二醛肟 在 水 、 铜 作用下， 生成 copper(II) dimethylglyoximate
  参考文献：
  名称：

  Ponzio, Gazzetta Chimica Italiana, 1921, vol. 51 II, p. 217

  摘要：

  DOI：

文献信息

• Efficient recyclable CuI-nanoparticle-catalyzed S-arylation of thiols with aryl halides on water under mild conditions
  作者：Hua-Jian Xu、Yu-Feng Liang、Xin-Feng Zhou、Yi-Si Feng

  DOI：10.1039/c2ob06795a

  日期：——

  nanoparticles efficiently catalyzed the C–S cross coupling of aryl and alkyl thiols with aryl halides in the absence of ligands on water under mild conditions. A wide range of diaryl sulfides and aryl alkyl sulfides are synthesized in good to excellent yields utilizing this protocol. This procedure is particularly noteworthy given its mild conditions, avoiding the undesired formation of disulfides through

  在不存在配体的情况下，CuI纳米颗粒可有效地催化芳基和烷基硫醇与芳基卤化物的C–S交叉偶联 水在温和的条件下。利用该方案，以良好至优异的产率合成了多种二芳基硫醚和芳基烷基硫醚。考虑到其温和的条件，该程序特别值得注意，可避免通过硫醇的氧化而形成不希望的二硫化物。描述了催化剂的回收和成功再利用。此外，提出了双芳基化产物的定向合成。
• Copper Iodide Nanoparticles-Catalysed Cyanation of Aryl Halides Using Non-Toxic K₄[Fe(CN)₆] in the Presence of 1,2-Bis(5-Tetrazolyl)Benzene as an Efficient Ligand
  作者：Mehdi Maham、Siavash Bahari

  DOI：10.3184/174751914x13966206828910

  日期：2014.5

  Cyanation of aryl bromides were carried out with K4[Fe(CN)6] in the presence of catalytic amounts of a copper salt and 1,2-bis(5-tetrazolyl)benzene as a ligand under thermal conditions. This method has the advantages of high yields, simple methodology and easy work up.

  在催化量的铜盐和1,2-双(5-四唑基)苯作为配体的存在下，在热条件下用K4[Fe(CN)6]进行芳基溴化物的氰化。该方法具有收率高、方法简单、易操作等优点。
• Bridging ability of a novel polydentate ligand (H2L) comprising an oxime function. Structures of a mononuclear precursor [NiL] and a dinuclear CuII2 complex. Magnetic properties of mononuclear (NiII and CuII), dinuclear (CuII2, NiII2, NiIICuII and CuIICrIII) and trinuclear (CuII3, CuIIMnIICuII and CuIIZnIICuII) complexes ‡
  作者：Jean-Pierre Costes、Françoise Dahan、Arnaud Dupuis、Jean-Pierre Laurent

  DOI：10.1039/a708374b

  日期：——

  A novel non-symmetrical polydentate Schiff base ligand 3-(2-[(1-methyl-3-oxobut-1-enyl)amino]ethyl}imino)butan-2-one oxime (H2L) comprising an oxime function among various donor sites yields neutral [NiIIL] and [CuIIL] complexes. The structural determination of [NiL] confirms the deprotonation of the oxime function. The deprotonated oxime oxygen atom can react with auxiliary complexes to give homo- and hetero-di- and tri-nuclear entities. The structural determination of a homodinuclear copper complex clearly shows the presence of the expected oxime bridge, along with an unexpected ketonic bridge between the two copper centres leading to a Cu[O,NO]Cu core. A moderate antiferromagnetic interaction is present in the di- and tri-nuclear copper complexes. A similar interaction is also observed in the heteronuclear complexes (CuIINiII and CuIIMnII) and, more surprisingly, in the heterodinuclear CuIICrIII entity. A generalization of the Cu[O,NO]Cu structure leads to a justification of these magnetic properties.

  一种新型不对称多齿Schiff碱配体3-(2-[(1-甲基-3-氧代丁-1-烯基)氨基]乙基}亚氨基)丁-2-酮肟(H2L)在多个供体位点间包含肟基功能，生成中性[NiIIL]和[CuIIL]配合物。[NiL]的结构确定确认了肟基功能的去质子化。去质子化的肟氧原子可以与辅助配合物反应，形成同核和异核的二核和三核实体。对同二核铜配合物的结构确定清晰地显示出预期的肟桥的存在，以及两个铜中心间意外的酮桥，从而形成了Cu[O,NO]Cu核。在二核和三核铜配合物中存在适度的反铁磁相互作用。在异核配合物（CuIINiII和CuIIMnII）中也观察到了类似的相互作用，更令人惊讶的是，在异二核CuIICrIII实体中也出现了这种相互作用。对Cu[O,NO]Cu结构的推广为这些磁性特性提供了合理解释。
• Preparation and characterization of CuI nanorods using Cu(dmg)2 as precursor via water-in-oil (w/o) microemulsions
  作者：Xue-Liang Li、Xiao-Yun Zhu、Ti-Lan Duan、Yi-Tai Qian

  DOI：10.1016/j.ssc.2006.04.025

  日期：2006.6

  Abstract CuI nanorods have been firstly prepared by water-in-oil microemulsions using Cu(dmg)2 as precursor at low temperature as low as 70 °C. X-ray diffraction (XRD) and transmission electron microscopy (TEM) measurements show that the CuI nanorods are pure γ-phase crystals with diameters ranging from 50 to 80 nm and lengths up to 500 nm. UV–vis spectrum reveals that the nanorods exhibit a blue shift

  摘要 以Cu(dmg)2 为前驱体，在低至70 °C 的低温条件下，首次通过油包水微乳液制备了CuI 纳米棒。X 射线衍射 (XRD) 和透射电子显微镜 (TEM) 测量表明，CuI 纳米棒是纯 γ 相晶体，直径范围为 50 至 80 nm，长度可达 500 nm。UV-vis 光谱显示纳米棒表现出蓝移并具有更宽的带隙能量。电化学阻抗谱 (EIS) 显示纳米棒具有更大的晶界电阻。对比实验结果表明，Cu(dmg)2晶体的棒状结构导致CuI晶体特别是单向生长，反相微乳液体系在使产品对称均匀方面起着至关重要的作用。
• Studies in nickel(IV) chemistry. Part 3. Kinetics of metal(II) ionmediated acid decomposition of tris(dimethylglyoximato)nickelate(IV) in aqueous medium
  作者：Gautam Neogi、Sridhara Acharya、Rama Krushna Panda、Dorai Ramaswamy

  DOI：10.1039/dt9830001239

  日期：——

  The kinetics of metal(II) ion-mediated acid decomposition of tris(dimethylglyoximato)nickelate(IV), [Ni(dmg)3]2–, with concomitant intramolecular electron transfer to produce [M(Hdmg)2] and Ni2+(aq) have been studied at 35 °C and ionic strength 0.57 mol dm–3 in aqueous medium in the range 3.6 ≲ pH ≲ 6.8. The reactions proceed via equilibrium formation of 1 : 1 adducts involving the protonated NiIV

  金属（II）离子介导的三（二甲基乙二肟基）镍酸酯（IV）[Ni（dmg）3 ] 2–的酸分解动力学，伴随分子内电子转移产生[M（Hdmg）2 ]和Ni 2+（aq）在35°C和0.57 mol dm –3的离子强度在3.6≲pH≲6.8的水性介质中进行了研究。反应通过平衡形成1：1的加合物进行，该加合物涉及质子化的Ni IV络合物和存在于介质中的M II（aq）（M = Cu，Zn或Ni）。与Cu II反应的速率决定步骤设想除了Ni IV配合物的质子辅助分解外，还涉及所形成的加合物的酸分解，与Zn II和Ni II反应的那些基本上通过与质子辅助分解平行的途径进行。Ni IV -Cu II反应中的Uv-可见光谱变化表明形成了1：1的加合物。