phthalocyanine Hf(IV) 5-sulfosalicylic acid | 380368-11-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: phthalocyanine Hf(IV) 5-sulfosalicylic acid
• 英文别名: hafnium(4+);2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene;2-oxido-5-sulfobenzoate
• CAS: 380368-11-6
• 化学式: C₃₉H₂₀HfN₈O₆S
• 分子量: 907.194
• InChiKey: CSYPBHXMLKIESA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  55
• 可旋转键数：
  1
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  202
• 氢给体数：
  1
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  dichloro(phthalocyaninato)hafnium(IV) 、 5-磺基水杨酸 以 further solvent(s) 为溶剂， 以84%的产率得到phthalocyanine Hf(IV) 5-sulfosalicylic acid
  参考文献：
  名称：

  Synthesis and spectral properties of axially substituted zirconium(IV) and hafnium(IV) water soluble phthalocyanines in solutions

  摘要：

  Methods of synthesis of novel water soluble axially substituted Zr(IV) and Hf(IV) phthalocyanines with gallic, 5-sulfosalicyllic, oxalic acids, and methyl ester of gallic acid as axial ligands coordinated to the central atom metal of phthalocyanine are presented. The absorption spectra of complex solutions in various solvents were characterized. The dependence of the spectral red shift from Reichardt's empirical polarity parameter is described. The deviation from the linearity of Beer-Bouguer-Lambert law was investigated for the range of concentration 5 x 10(-6) to 10 x 10(-5) M. Fluorescent properties of axially substituted phthalocyaninato metal complexes in DMSO solutions were investigated. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2004.03.090