zinc(II) α-nitroso-β-naphtholate | 31006-66-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: zinc(II) α-nitroso-β-naphtholate
• 英文别名: ZINC;2-nitrosonaphthalen-1-olate
• CAS: 31006-66-3
• 化学式: C₂₀H₁₂N₂O₄Zn
• 分子量: 409.716
• InChiKey: JRODSYLYRDQESE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.62
• 重原子数：
  27
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  105
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  octaphenyltetraazaporphyrin 、 zinc(II) α-nitroso-β-naphtholate 以 二甲基亚砜 为溶剂， 生成 (2,3,7,8,12,13,17,18-octaphenyl-5,10,15,20-tetraazaporphyrinato)zinc(II)
  参考文献：
  名称：

  摘要：

  Coordination of three azaporphines, namely, octaphenyltetraazaporphine (I), octa(4-nitrophenyl)-tetraazaporphine (II), and octa(4-bromophenyl)-tetraazaporphine (III) with some chelate salts of copper and zinc (hydroxyquinolate (IV), alpha-nitroso-beta-naphtholate (V), glycinate (VI), alaninate (VII), valinate (VIII), leucinate (IX), and glutaminate (X)) in DMSO were studied. As in the case with acetates, compound I was found to coordinate chelate salts according to the monomolecular mechanism and to give amino complex with the bridging nitrogen atom. Compound II reacts with all indicated salts according to the bimolecular mechanism almost instantaneously, except for VII. In the same way, reactions of III are also instantaneous, even with VII. Coordination of I with Zn(II) chelate salts proceeds at the rates higher than with acetate.

  DOI：

  10.1023/a:1023679902785