N,N-diisopropyl-2,3-diphenylpropylamine | 76233-27-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: N,N-diisopropyl-2,3-diphenylpropylamine
• 英文别名: 2,3-diphenyl-N,N-di(propan-2-yl)propan-1-amine
• CAS: 76233-27-7
• 化学式: C₂₁H₂₉N
• 分子量: 295.468
• InChiKey: MHSFJIQKRIRCJL-UHFFFAOYSA-N

物化性质

• 沸点：
  381.0±31.0 °C(Predicted)
• 密度：
  0.961±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.13
• 重原子数：
  22.0
• 可旋转键数：
  7.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  N,N-diisopropyl-2,3-diphenylpropylamine 、 碘甲烷 反应 1.0h， 生成 N,N-diisopropyl-2,3-diphenylpropylamine methiodide salt
  参考文献：
  名称：

  Photochemical addition of tertiary amines to stilbene. Stereoelectronic control of tertiary amine oxidation

  摘要：

  DOI：

  10.1021/jo00319a007
• 作为产物：
  描述：

  反式-1,2-二苯乙烯 、 N,N-二异丙基甲胺 以 乙腈 为溶剂， 反应 19.0h， 以95%的产率得到N,N-diisopropyl-2,3-diphenylpropylamine
  参考文献：
  名称：

  Photochemical addition of tertiary amines to stilbene. Stereoelectronic control of tertiary amine oxidation

  摘要：

  DOI：

  10.1021/jo00319a007

文献信息

• Photochemistry of stilbene-amine. Spin-trapping study
  作者：Chiou Rong Lin、Cheng Nan Wang、Tong Ing Ho

  DOI：10.1021/jo00017a009

  日期：1991.8

  2-Methyl-2-nitrosopropane (MNP) was used as a spin-trap reagent to study the radicals formed in the photochemical reaction of substituted trans-stilbenes (TS) with tertiary amines. Seven 1,2-(p,p'-disubstitited phenyl)ethyl radicals were trapped by MNP and isolated and identified by HPLC-EPR. The nitrogen hyperfine splitting constants (hfsc) of these radicals are linearly correlated with the Hammett substituent constants sigma-P. There is also a linear correlation of the nitrogen hfsc with both the single sigma-P parameter and the dual sigma-R', sigma-I parameters. The inductive and resonance effects are of equal importance. The correlation between proton hfsc and a single sigma-P parameter is not linear. There is fair correlation between the beta-proton hfsc and the dual parameters sigma-R', sigma-I. The only fair correlation may be due to the large dihedral angle between the nitrogen pi orbital and the N-C-H plane.
• Selectivity of tertiary amine oxidations
  作者：Frederick D. Lewis、Tong-Ing Ho

  DOI：10.1021/ja00525a061

  日期：1980.2
• LEWIS F. D.; HO TONG-ING, J. AMER. CHEM. SOC., 1980, 102, NO 5, 1751-1752
  作者：LEWIS F. D.、 HO TONG-ING

  DOI：——

  日期：——