trans,cis-[Pt((15)N-en)(OH)2I2] | 229483-14-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: trans,cis-[Pt((15)N-en)(OH)2I2]
• CAS: 229483-14-1
• 化学式: C₂H₁₀I₂N₂O₂Pt
• 分子量: 544.989
• InChiKey: GPXNESXHNFCJDF-IIZUGCCDSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans,cis-[Pt((15)N-en)(OH)2I2] 在 guanosine-5'-monophosphate 作用下， 以 水 、 重水 为溶剂， 生成
  参考文献：
  名称：

  Nucleotide Platination Induced by Visible Light

  摘要：

  A two-step photoreaction is induced by irradiation of the PtIV complex trans,cis-[Pt(OCOCH3 )2 I2 (en)] with visible light in the presence of guanosine 5'-monophosphate (5'-GMP; see scheme): A photoinduced ligand exchange followed by photoreduction gives the bis-GMP adduct of [Pt(en)]2+ . Although the dihydroxodiiodo complex also undergoes a photoinduced ligand exchange, no reaction with the nucleotide was observed.

  DOI：

  10.1002/(sici)1521-3773(19990517)38:10<1460::aid-anie1460>3.0.co;2-z
• 作为产物：
  描述：

  、 鸟苷酸 以 水 、 重水 为溶剂， 生成 {Pt(guanosine 5'-monophosphate-N7)2((15)NH2CH2CH2(15)NH2)}(2+) 、 trans,cis-[Pt((15)N-en)(OH)2I2] 、
  参考文献：
  名称：

  Nucleotide Platination Induced by Visible Light

  摘要：

  A two-step photoreaction is induced by irradiation of the PtIV complex trans,cis-[Pt(OCOCH3 )2 I2 (en)] with visible light in the presence of guanosine 5'-monophosphate (5'-GMP; see scheme): A photoinduced ligand exchange followed by photoreduction gives the bis-GMP adduct of [Pt(en)]2+ . Although the dihydroxodiiodo complex also undergoes a photoinduced ligand exchange, no reaction with the nucleotide was observed.

  DOI：

  10.1002/(sici)1521-3773(19990517)38:10<1460::aid-anie1460>3.0.co;2-z