2-(tetrahydro-2-thienyl)phenol S-Oxide | 119019-43-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-(tetrahydro-2-thienyl)phenol S-Oxide
• 英文别名: 2-(1-Oxothiolan-2-yl)phenol
• CAS: 119019-43-1
• 化学式: C₁₀H₁₂O₂S
• 分子量: 196.27
• InChiKey: XFFQPQMWQKLWET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  56.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(tetrahydro-2-thienyl)phenol S-Oxide 生成 [2-(thiolan-2-yl)phenyl] N-propan-2-ylcarbamate
  参考文献：
  名称：

  MISHRA, ANUPAMA;MOORE, RICHARD C.

  摘要：

  DOI：
• 作为产物：
  描述：

  2-(tetrahydro-thien-2-yl)-phenol 以 甲醇 、 水 为溶剂， 生成 2-(tetrahydro-2-thienyl)phenol S-Oxide
  参考文献：
  名称：

  2-(tetrahydro-2-thienyl)phenols and carbamate derivatives thereof

  摘要：

  化合物的结构式为##STR1##其中R为C.sub.1-C.sub.6烷基或C.sub.5-C.sub.6环烷基；X为氢或甲基；R.sup.1，R.sup.2，R.sup.3和R.sup.4相同或不同，为氢，卤素，C.sub.1-C.sub.8烷基，C.sub.1-C.sub.2卤代烷基，C.sub.3-C.sub.6环烷基，C.sub.7-C.sub.9芳基烷基，苯基，硝基，C.sub.1-C.sub.6烷氧基，C.sub.1-C.sub.6烷基硫基，C.sub.1-C.sub.6烷基亚砜基，C.sub.1-C.sub.6烷基磺酰基，C.sub.7-C.sub.9芳基烷氧基，苯氧基，苯基硫基，苯基亚砜基，苯基磺酰基，四氢-2-噻吩基，二氧化四氢-2-噻吩基，碱金属羧酸盐，C.sub.2-C.sub.5烷氧羰基，苯氧羰基或N(R.sup.5)R.sup.6；R.sup.5和R.sup.6相同或不同，为氢或C.sub.1-C.sub.2烷基；n为0、1或2。还公开了使用该化合物的杀虫剂有效量来控制昆虫的方法。此外，还提供了含有该化合物的杀虫剂有效量和载体的杀虫剂组合物。该公开进一步阐述了化合物的结构式##STR2##其中R.sup.1，R.sup.2，R.sup.3和R.sup.4相同或不同，为氢，卤素，C.sub.1-C.sub.8烷基，C.sub.1-C.sub.2卤代烷基，C.sub.3-C.sub.6环烷基，C.sub.7-C.sub.9芳基烷基，苯基，硝基，C.sub.1-C.sub.6烷氧基，C.sub.1-C.sub.6烷基硫基，C.sub.1-C.sub.6烷基亚砜基，C.sub.1-C.sub.6烷基磺酰基，C.sub.7-C.sub.9芳基烷氧基，苯氧基，苯基硫基，苯基亚砜基，苯基磺酰基，四氢-2-噻吩基，二氧化四氢-2-噻吩基，碱金属羧酸盐，C.sub.2-C.sub.5烷氧羰基，苯氧羰基或N(R.sup.5)R.sup.6；R.sup.5和R.sup.6相同或不同，为氢或C.sub.1-C.sub.2烷基；n为0、1或2，但当R.sup.2，R.sup.3和R.sup.4均为氢且n为0时，R.sup.1不能为甲基。该类化合物用于制备本发明的氨基甲酸酯化合物的过程中。

  公开号：

  US04778819A1

文献信息

• MISHRA, ANUPAMA;MOORE, RICHARD C.
  作者：MISHRA, ANUPAMA、MOORE, RICHARD C.

  DOI：——

  日期：——
• 2-(tetrahydro-2-thienyl)phenols and carbamate derivatives thereof
  申请人：Uniroyal Chemical Company, Inc.

  公开号：US04778819A1

  公开（公告）日：1988-10-18

  A compound having the structural formula ##STR1## where R is C.sub.1 -C.sub.6 alkyl or C.sub.5 -C.sub.6 cycloalkyl; X is hydrogen or methyl; R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are the same or different and are hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.2 haloalkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.7 -C.sub.9 aralkyl, phenyl, nitro, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylthio, C.sub.1 -C.sub.6 alkylsulfinyl, C.sub.1 -C.sub.6 alkylsulfonyl, C.sub.7 -C.sub.9 aralkoxy, phenoxy, phenylthio, phenylsulfinyl, phenylsulfonyl, tetrahydro-2-thienyl, dioxytetrahydro-2-thienyl, alkali metal carboxylate, C.sub.2 -C.sub.5 alkoxycarbonyl, phenoxycarbonyl or N(R.sup.5)R.sup.6 ; R.sup.5 and R.sup.6 are the same or different and are hydrogen or C.sub.1 -C.sub.2 alkyl; and n is 0, 1 or 2 is disclosed. A method for controlling insects using an insectidically effective amount of this compound is also taught. In addition, an insecticidal composition comprising an insecticidally effective amount of the compound and a carrier therefor is provided. The disclosure further sets forth a compound having the structural formula ##STR2## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are the same or different and are hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.2 haloalkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.7 -C.sub.9 aralkyl, phenyl, nitro, C.sub.1 -C.sub.6 alkoxy, C.sub.1 -C.sub.6 alkylthio, C.sub.1 -C.sub.6 alkylsulfinyl, C.sub.1 -C.sub.6 alkylsulfonyl, C.sub.7 -C.sub.9 aralkoxy, phenoxy, phenylthio, phenylsulfinyl, phenylsulfonyl, tetrahydro-2-thienyl, dioxytetrahydro-2-thienyl, alkali metal carboxylate, C.sub.2 -C.sub.5 alkoxycarbonyl, phenoxycarbonyl or N(R.sup.5)R.sup.6 ; R.sup.5 and R.sup.6 are the same or different and are hydrogen or C.sub.1 -C.sub.2 alkyl; and n is 0, 1 or 2 with the proviso that when R.sup.2, R.sup.3 and R.sup.4 are all hydrogen and n is 0, R.sup.1 cannot be methyl, This class of compounds is used in the process, disclosed herein, for making the carbamate compounds of the present invention.

  化合物的结构式为##STR1##其中R为C.sub.1-C.sub.6烷基或C.sub.5-C.sub.6环烷基；X为氢或甲基；R.sup.1，R.sup.2，R.sup.3和R.sup.4相同或不同，为氢，卤素，C.sub.1-C.sub.8烷基，C.sub.1-C.sub.2卤代烷基，C.sub.3-C.sub.6环烷基，C.sub.7-C.sub.9芳基烷基，苯基，硝基，C.sub.1-C.sub.6烷氧基，C.sub.1-C.sub.6烷基硫基，C.sub.1-C.sub.6烷基亚砜基，C.sub.1-C.sub.6烷基磺酰基，C.sub.7-C.sub.9芳基烷氧基，苯氧基，苯基硫基，苯基亚砜基，苯基磺酰基，四氢-2-噻吩基，二氧化四氢-2-噻吩基，碱金属羧酸盐，C.sub.2-C.sub.5烷氧羰基，苯氧羰基或N(R.sup.5)R.sup.6；R.sup.5和R.sup.6相同或不同，为氢或C.sub.1-C.sub.2烷基；n为0、1或2。还公开了使用该化合物的杀虫剂有效量来控制昆虫的方法。此外，还提供了含有该化合物的杀虫剂有效量和载体的杀虫剂组合物。该公开进一步阐述了化合物的结构式##STR2##其中R.sup.1，R.sup.2，R.sup.3和R.sup.4相同或不同，为氢，卤素，C.sub.1-C.sub.8烷基，C.sub.1-C.sub.2卤代烷基，C.sub.3-C.sub.6环烷基，C.sub.7-C.sub.9芳基烷基，苯基，硝基，C.sub.1-C.sub.6烷氧基，C.sub.1-C.sub.6烷基硫基，C.sub.1-C.sub.6烷基亚砜基，C.sub.1-C.sub.6烷基磺酰基，C.sub.7-C.sub.9芳基烷氧基，苯氧基，苯基硫基，苯基亚砜基，苯基磺酰基，四氢-2-噻吩基，二氧化四氢-2-噻吩基，碱金属羧酸盐，C.sub.2-C.sub.5烷氧羰基，苯氧羰基或N(R.sup.5)R.sup.6；R.sup.5和R.sup.6相同或不同，为氢或C.sub.1-C.sub.2烷基；n为0、1或2，但当R.sup.2，R.sup.3和R.sup.4均为氢且n为0时，R.sup.1不能为甲基。该类化合物用于制备本发明的氨基甲酸酯化合物的过程中。