(propylideneamino)phenol | 38421-50-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: (propylideneamino)phenol
• 英文别名: 2-(Propylideneamino)phenol
• CAS: 38421-50-0
• 化学式: C₉H₁₁NO
• 分子量: 149.192
• InChiKey: WYGKNNMTBKQNFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  32.6
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  二氧化三碳 、 (propylideneamino)phenol 以 乙醚 为溶剂， 以61%的产率得到4-oxo-5-propylidene-1,5-benzoxazepin-5-ium-2-olate
  参考文献：
  名称：

  Novel Syntheses with Carbon Suboxide; III. Cyclocondensation with N-Benzylidene- or N-Propylidene-2-hydroxyanilines to form the Seven-Membered Ring System of 5-Benzyl(propyl)idene-4-oxido-2-oxo-2,5-dihydro-1,5-benzoxazepinium Betaines

  摘要：

  DOI：

  10.1055/s-1982-30010

文献信息

• Construction of functionalized 2,3-dihydro-1,4-benzoxazines via [5 + 1] annulations of 2-halo-1,3-dicarbonyl compounds with imines
  作者：Ya-Ru Zhang、Jian-Wu Xie、Xu-Jiao Huang、Wei-Dong Zhu

  DOI：10.1039/c2ob25927c

  日期：——

  A series of functionalized 2,3-dihydro-1,4-benzoxazines were obtained in moderate to excellent yields via domino [5 + 1] annulations of 2-halo-1,3-dicarbonyl compounds 2 with imines 1 under mild conditions and the application of this method in the synthesis of bioactive analogues, such as functionalized tetracyclic-1,4-benzoxazines which contain two new heterocyclic rings and one quaternary carbon

  在中度得到以优异的产率的一系列官能化2,3-二氢-1,4-苯并恶嗪的经由多米诺[5 + 1] 2-卤代-1,3-二羰基的化合物annulations 2与亚胺1温和的条件和所述下还开发了该方法在生物活性类似物合成中的应用，例如含有两个新的杂环和一个季碳中心的功能化四环-1,4-苯并恶嗪。
• Synthesis and Crystal Structure of 2-Substituted 3-Aryl-2-Oxophenylbenzo[<i>E</i>]-1,4,2-Oxazaphosphinanes
  作者：Mudaris Dimukhametov、Natalya Belova、Vladimir Mironov、Ekaterina Mironova、Dmitry Krivolapov、Petro Onys’ko、Yulia Rassukanaya

  DOI：10.1080/10426507.2014.993756

  日期：2015.6.3

  GRAPHICAL ABSTRACT Abstract Stereoisomers of 2-substituted 3-aryl-2-oxobenzo[e]-1,4,2-oxazaphosphinane derivatives were obtained by the phosphorylation of 2-arylideneaminophenols with dichlorophenylphosphine in the presence of triethylamine followed by the water treatment, which were isolated by column chromatography as pure diastereoisomers. Their structure was determined by NMR and XRD.

  图形摘要摘要 2-取代的 3-芳基-2-氧代苯并[e]-1,4,2-氧氮杂膦烷衍生物的立体异构体是通过在三乙胺存在下用二氯苯基膦磷酸化 2-亚芳基氨基苯酚，然后进行水处理获得的。通过柱色谱法分离出纯非对映异构体。它们的结构由NMR和XRD确定。
• COMPOSITIONS AND RELATED METHODS FOR AGRICULTURE
  申请人：Flagship Pioneering Innovations V, Inc.

  公开号：US20210289794A1

  公开（公告）日：2021-09-23

  The invention comprises methods for decreasing colonization by a bacterium of a gut of a stink bug, the method comprising providing a composition comprising vanillin or an analog thereof; and delivering said composition to an egg from which the stink bug will hatch, whereby colonization by the bacterium within the gut of the stink bug hatched from the egg treated with the composition is decreased relative to a stink bug hatched from an untreated egg. In some embodiments, the decrease in colonization by the bacterium decreases the fitness of the stink bug, e.g., decreases reproductive ability, survival, rate of development, number of eggs, number of hatched eggs, adult emergence rate, body length, body width, body mass, or cuticle thickness. In some embodiments of the methods herein, the bacterial colonization-disrupting agent is an inhibitor of bacterial metabolism. In some embodiments, the bacterial colonization-disrupting agent is a polyhydroxyalkanoate (PHA) synthesis inhibitor.