[(Bu)2(C2H5C4N(CH3)2CHC4N(CH3)(C2H5)C4H3N)Sn] | 1318245-48-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [(Bu)2(C2H5C4N(CH3)2CHC4N(CH3)(C2H5)C4H3N)Sn]
• CAS: 1318245-48-5
• 化学式: C₂₈H₄₁N₃Sn
• 分子量: 538.364
• InChiKey: XSRVHGNZKHYIFT-LVQJZLIHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 二正丁基氧化锡 以 甲醇 为溶剂， 以22%的产率得到[(Bu)2(C2H5C4N(CH3)2CHC4N(CH3)(C2H5)C4H3N)Sn]
  参考文献：
  名称：

  Synthesis and Characterization of Fluorescent Pyrrolyldipyrrinato Sn(IV) Complexes

  摘要：

  A series of neutral, 5-coordinate pyrrolyldipyrrinato Sn(IV) complexes have been synthesized via reaction of a pyrrolyldipyrrin, or its corresponding hydrochloride salt, with dibutyltin or diphenyltin oxide. The complexes are structurally unique in that all three nitrogen atoms of the pyrrolyldipyrrinato ligand bind to the tin center, making these complexes the first examples of pyrrolyldipyrrins behaving as LX2 ligands. The complexes are highly fluorescent, exhibiting fluorescence quantum yields between 0.28 and 0.61, and display interesting preliminary biological activity.

  DOI：

  10.1021/ic200731t