| 1610791-92-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1610791-92-8；1612156-47-4；1612156-48-5
• 化学式: C₅₂H₃₂N₄O₃Zn
• 分子量: 826.241
• InChiKey: XAMPBMHEQQXDRX-ICMLAEDQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 D-苯丙氨酸甲酯 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Chiral dinaphthylporphyrin with C2 symmetry: synthesis, resolution, and enantio-discrimination by single-crystal X-ray diffraction analysis

  摘要：

  An intrinsic chiral dinaphthylporphyrin with C-2 symmetry, namely [5,15-trans-bis(2-hydroxynaphthyl)-10-phenyl-20-(4-hydroxyphenyl)porphyrinato]zinc(II) (ZnDNP), has been designed and synthesized. The molecular structure of ZnDNP was determined by single crystal X-ray diffraction analysis. Resolution of the racemic mixture was achieved with chiral HPLC technique. In particular, the stereostructures of the enantiomers and the specific interactions between the chiral meso-dinaphthylporphyrin with L-Phe-OMe were elucidated in the solid state by single-crystal X-ray diffraction analysis. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.04.067
• 作为产物：
  描述：

  zinc(II) acetate dihydrate 、 trans-5,15-bis(2-hydroxynaphthyl)-10-phenyl-20-(4-hydroxyphenyl)porphyrin 以 甲醇 、 氯仿 为溶剂， 反应 12.0h， 以60%的产率得到
  参考文献：
  名称：

  Chiral dinaphthylporphyrin with C2 symmetry: synthesis, resolution, and enantio-discrimination by single-crystal X-ray diffraction analysis

  摘要：

  An intrinsic chiral dinaphthylporphyrin with C-2 symmetry, namely [5,15-trans-bis(2-hydroxynaphthyl)-10-phenyl-20-(4-hydroxyphenyl)porphyrinato]zinc(II) (ZnDNP), has been designed and synthesized. The molecular structure of ZnDNP was determined by single crystal X-ray diffraction analysis. Resolution of the racemic mixture was achieved with chiral HPLC technique. In particular, the stereostructures of the enantiomers and the specific interactions between the chiral meso-dinaphthylporphyrin with L-Phe-OMe were elucidated in the solid state by single-crystal X-ray diffraction analysis. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2014.04.067