[(4-chlorobenzyl)Co(N,N'-diphenylglyoximato)2(C5H5N)] | 217814-33-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(4-chlorobenzyl)Co(N,N'-diphenylglyoximato)2(C5H5N)]
• CAS: 217814-33-0
• 化学式: C₄₀H₃₃ClCoN₅O₄
• 分子量: 742.179
• InChiKey: DCQRVZQHSFNHGX-AGMWPDPBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(4-chlorobenzyl)Co(N,N'-diphenylglyoximato)2(C5H5N)] 、 二氧化硫 以 四氢呋喃 为溶剂， 以40%的产率得到[(4-chlorobenzylSO2)Co(N,N'-diphenylglyoximato)2(C5H5N)]
  参考文献：
  名称：

  二氧化硫插入有机碳氧化合物中的Co-C键：晶体结构和Co-C键反应性†研究

  摘要：

  将二氧化硫插入ArCH 2 Co（dioxime）2 Py的Co-C键中形成ArCH 2 SO 2 Co（dioxime ）2 Py，ClCo（dioxime）2 Py和中性三核络合物的混合物，[[ dpgH）2 PyCo III -μ-SO 3 ] 2钴II（甲醇）4。插入的产品4-CN-C 6 H 4 CH 2 SO 2 Co（dpgH）2 Py和C 6 H 5 CH 2 SO 2 Co（gH）2Py和三核复合物首次通过X射线进行了结构表征。将二氧化硫插入Co-C键会影响苄基的方向。

  DOI：

  10.1021/om0507171
• 作为产物：
  描述：

  [Co(pyridine)Cl(glyoximato)(diphenylglyoximato)] 在 NaOH 、 sodium borohydride 、 acetic acid 作用下， 以 甲醇 、 水 为溶剂， 生成 [(4-chlorobenzyl)Co(N,N'-diphenylglyoximato)2(C5H5N)] 、 [Co(pyridine)(4-Cl-C6H4CH2)(glyoximato)(diphenylglyoximato)]
  参考文献：
  名称：

  Molecular Oxygen Insertion in Benzylcobaloximes with Mixed Dioximes

  摘要：

  The complexes ArCH2CO(gH)(dpgH)Py have been synthesized and characterized by NMR. Molecular oxygen insertion into the Co-C bond in ArCH2CO(L)(dpgH)Py (L = gH, dmgH, chgH) complexes under photochemical conditions forms a mixture of products within 5 min. The equilibration/decomposition of ArCH2Co(L)(dpgH)Py to the corresponding ArCH2Co(L)(2)Py and ArCH2Co(dpgH)(2)Py complexes and molecular oxygen insertion starts immediately and simultaneously. The ratio of these products changes with time, and finally ArCH2(O-2)Co(L)(dpgH)Py and ArCH2(O-2)Co(dpgH)(2)Py are the major products formed. The spectral data are interrelated, and a good correlation is found between Delta delta(1)(H)(Py-alpha) and delta(13C)(C=N-gH) or delta(13C)(C=N-dpgH), indicating ring current throughout the metallabicycle. The CV data show that the dioxy complex is easier to reduce than the parent complex. The molecular structure of 4-Cl-C6H4CH2Co(dpgH)(gH)Py has been reported.

  DOI：

  10.1021/om700938w

文献信息

• Organocobaloximes with mixed dioxime equatorial ligands: a convenient one-pot synthesis. X-ray crystal structures of BnCoIII(dmgH)(dpgH)Py and BnCOIII(chgH)(dpgH)py
  作者：B.D Gupta、R Yamuna、Veena Singh、Usha Tiwari、T Barclay、W Cordes

  DOI：10.1016/s0022-328x(01)00731-8

  日期：2001.5

  A simple and general route to the synthesis of organocobaloxime with mixed dioxime ligands, RCo(dmgH)(dpgH)Py and RCo(chgH)(dpgH)Py, has been described. The C-13-NMR chemical shifts have been analysed to see whether one dioxime wing has any effect on the other dioxime wing. The first crystal structure of an organocobaloxime with mixed dioxime ligand in the same complex, BnCo(dmgH)(dpgH)Py and BnCo(chgH)(dpgH)Py, is reported. (C) 2001 Published by Elsevier Science B.V.