Sb(1-C10H7)3Cl2 | 52762-61-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Sb(1-C10H7)3Cl2
• 英文别名: tri(α-naphthyl)antimony(III) dichloride；tri-[1]naphthyl antimony (2+); dichloride；Tri-[1]naphthyl-antimon(2+); Dichlorid；dichloro(trinaphthalen-1-yl)-λ5-stibane
• CAS: 52762-61-5
• 化学式: C₃₀H₂₁Cl₂Sb
• 分子量: 574.153
• InChiKey: QGHWVOONOHTHJA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.04
• 重原子数：
  33.0
• 可旋转键数：
  3.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  2-呋喃甲酸钠盐 、 Sb(1-C10H7)3Cl2 以 甲醇 、 苯 为溶剂， 以68%的产率得到tri(α-naphthyl)antimony(V) (OOC(C4H3O))(Cl)
  参考文献：
  名称：

  STUDIES ON STERICALLY HINDERED TRI(α-NAPHTHYL)ANTIMONY(V) AMIDE, CARBOXYLATE, AND OXIME DERIVATIVES

  摘要：

  Several hitherto unreported penta-coordinate tri(alpha-naphthyl)antimony(V) haloimides, haloamines, halocarboxylates and dioximates of the general formulas (alpha-C10H7)(3)SbLX and (alpha-C10H7)(3)SbL2 (where L=amides, amines, carboxylates and oximes; X=halogens) have been prepared by the metathesis reaction of (alpha-C10H7)(3)SbX2 with the appropriate metals salts of the organic ligands. The amide derivatives were also obtained by the addition of N-halo amides to tri(alpha-naphthyl)-antimony(V). The newly synthesised compounds have been characterised by conventional methods. A tentative trigonal bipyramidal structure is suggested for these compounds. The failure to replace the second halogen atom in (alpha-C10H7)(3)SbXL may be attributed to steric hindrance offered by the naphthyl groups bound to antimony as well as the bulky nature of the organic ligand.

  DOI：

  10.1081/sim-120003788
• 作为产物：
  描述：

  1-溴代萘 在 lithium 、 Cl₂ 作用下， 以 not given 为溶剂， 生成 Sb(1-C10H7)3Cl2
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sb: Org.Comp.1, 1.1.1.1.10, page 107 - 108

  摘要：

  DOI：

文献信息

• Synthese, marquage radiochimique et proprietes de quelques aryl- et alkylstibines et de leurs derives halogenes
  作者：M. Benmalek、H. Chermette、C. Martelet、D. Sandino、J. Tousset

  DOI：10.1016/s0022-328x(00)93683-0

  日期：1974.1

  Direct condensation of alkyl- or arylmagnesium halide on antimony trichloride has been used for synthesis of labelled stibines. Trialkyl- or triarylantimony difluorides can be obtained with good yields by means of solvent extraction from corresponding halides. Some partition coefficient values obtained with radiochemical labelling are given. Hydrolysis of these compounds has been studied.

  烷基或芳基卤化镁在三氯化锑上的直接缩合已用于合成标记的stibines。通过从相应的卤化物中萃取溶剂，可以以良好的收率获得三烷基三芳基或三芳基锑二氟化物。给出了通过放射化学标记获得的一些分配系数值。已经研究了这些化合物的水解。
• CIV.—The action of inorganic halides on organometallic compounds
  作者：Frederick Challenger、Freda Pritchard

  DOI：10.1039/ct9242500864

  日期：——
• Challenger; Pritchard, Journal of the Chemical Society, 1924, vol. 125, p. 871
  作者：Challenger、Pritchard

  DOI：——

  日期：——
• Matsumiya, K., 1925, vol. 8, p. 11 - 18
  作者：Matsumiya, K.

  DOI：——

  日期：——