methyl 2-(N-tert-butyl-N-(1-diethylphosphono-2,2-dimethylpropyl)aminooxy)propionate | 300811-93-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: methyl 2-(N-tert-butyl-N-(1-diethylphosphono-2,2-dimethylpropyl)aminooxy)propionate
• 英文别名: N-tert-butyl-N-1-diethylphosphono-2,2-dimethylpropyl-O-1-methoxycarbonylethylhydroxylamine；N-tert-butyl-N-1-diethylphophono-2,2-dimethylpropyl-O-1-methoxycarbonylethylhydroxylamine；2-methyl-2-[N-[1-(diethoxyphosphinyl)-2,2-dimethylpropyl]aminoxy]propionic acid methyl ester；Methyl 2-[tert-butyl-(1-diethoxyphosphoryl-2,2-dimethylpropyl)amino]oxypropanoate
• CAS: 300811-93-2
• 化学式: C₁₇H₃₆NO₆P
• 分子量: 381.45
• InChiKey: CGQYROIODZDURG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  25
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  74.3
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  methyl 2-(N-tert-butyl-N-(1-diethylphosphono-2,2-dimethylpropyl)aminooxy)propionate 在 sodium hydroxide 、 水 、 盐酸 作用下， 以 甲醇 、 水 为溶剂， 反应 24.0h， 以90%的产率得到2-[N-tert-butyl-N-(1-diethoxyphosphoryl-2,2-dimethylpropyl)aminoxy]propionic acid
  参考文献：
  名称：

  Alkoxyamines derived from beta-phosphorylated nitroxides, and use thereof for preparing polymerized or non-polymerized mono-or polyalkoxyamines

  摘要：

  该发明涉及使用式(I)的烷氧胺来制备式(II)的聚合或非聚合的单烷氧胺或多烷氧胺。

  公开号：

  US20050065119A1

文献信息

• Alkoxyamines derived from beta-phosphorylated nitroxides, and use thereof for preparing polymerized or non-polymerized mono-or polyalkoxyamines
  申请人：Couturier Jean-luc

  公开号：US20050065119A1

  公开（公告）日：2005-03-24

  The invention relates to the use of alkoxyamines of formula (I): for the preparation of polymerized or non-polymerized mono- or polyalkoxyamines of formula (II):

  该发明涉及使用式(I)的烷氧胺来制备式(II)的聚合或非聚合的单烷氧胺或多烷氧胺。
• Process for the preparation of sterically hindered nitroxyl ethers
  申请人：Schöning Kai-Uwe

  公开号：US20100249401A1

  公开（公告）日：2010-09-30

  The present invention relates to a novel process for the preparation of a sterically hindered nitroxyl ether from the corresponding sterically hindered nitroxyl radical by reacting it with a carbonyl compound and a hydroperoxide. The compounds prepared by this process are effective stabilizers for polymers against harmful effects of light, oxygen and/or heat, as flame-retardants for polymers and as polymerization regulators.

  本发明涉及一种从相应的立体位阻的亚硝基自由基通过与羰基化合物和过氧化氢反应制备立体位阻的亚硝基醚的新工艺。通过该工艺制备的化合物是聚合物的有效稳定剂，可抵抗光、氧和/或热的有害影响，作为聚合物的阻燃剂和聚合物化合物的调节剂。
• Alkoxyamine-Mediated Radical Synthesis of Indolinones and Indolines
  作者：Corinne Leroi、Denis Bertin、Pierre-Emmanuel Dufils、Didier Gigmes、Sylvain Marque、Paul Tordo、Jean-Luc Couturier、Olivier Guerret、Marco A. Ciufolini

  DOI：10.1021/ol0358049

  日期：2003.12.1

  [GRAPHICS]Thermolysis of alpha-alkoxyamino propionanilides produces indolinones, whereas thermal reaction of N-allylaniline derivatives with various Tordo-type alkoxyamines results in formation of indolines in the radical regime.
• ALCOXYAMINES ISSUES DE NITROXYDE BETA-PHOSPHORES, LEUR UTILISATION EN POLYMERISATION RADICALAIRE
  申请人：Atofina

  公开号：EP1153030B1

  公开（公告）日：2002-09-11
• Controlled radical acrylic copolymer thickeners
  申请人：Schmidt Charles Scott

  公开号：US20070082827A1

  公开（公告）日：2007-04-12

  The present invention relates to acrylic block copolymers synthesized by a controlled radical process, and their use as thickeners in oil-based compositions. The acrylic copolymers are especially useful as viscosity index improvers in lubricating oil.