3-thiophenecarbaldehyde N-[-3-thienylmethylidene]hydrazone | 17303-96-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3-thiophenecarbaldehyde N-[-3-thienylmethylidene]hydrazone
• 英文别名: 1,2-bis((thiophen-3-yl)methylene)hydrazine；1-thiophen-3-yl-N-(thiophen-3-ylmethylideneamino)methanimine
• CAS: 17303-96-7
• 化学式: C₁₀H₈N₂S₂
• 分子量: 220.319
• InChiKey: GOWRAELJMIBCNE-UHFFFAOYSA-N

物化性质

• 熔点：
  150-151 °C(Solv: ethyl acetate (141-78-6))
• 沸点：
  332.6±30.0 °C(Predicted)
• 密度：
  1.25±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  81.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  silver hexafluoroantimonate 、 3-thiophenecarbaldehyde N-[-3-thienylmethylidene]hydrazone 以 甲醇 、 二氯甲烷 为溶剂， 以43%的产率得到[Ag(1,2-bis((thiophen-3-yl)methylene)hydrazine)2][SbF6]
  参考文献：
  名称：

  Bi(thipohene)-type ligand and its silver coordination polymers [AgL2]·(X) (L=1,2-bis((thiophen-3-yl)methylene)hydrazine; )

  摘要：

  A novel linking ligand, 1,2-bis((thiophen-3-yl)methylene)hydrazine (L), which contains terminal thiophene rings, was prepared. From ligand L and silver salts AgX, the corresponding 2-D silver coordination polymers [AgL2] center dot (X) [X = ClO4- (1), SbF6- (2), PF6- (3)] could be prepared. All polymers have been constructed by van der Waals contacts, and their structures depend basically on the nature of the counterions used. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.06.011
• 作为产物：
  描述：

  7-hydroxy-6,7-azabora-thieno<3,2-c>pyridine 在 sodium hydroxide 作用下， 以 not given 为溶剂， 以71%的产率得到3-thiophenecarbaldehyde N-[-3-thienylmethylidene]hydrazone
  参考文献：
  名称：

  Gronowitz,S.; Namtvedt,J., Acta Chemica Scandinavica (1947), 1967, vol. 21, p. 2151 - 2166

  摘要：

  DOI：

文献信息

• Thermolysis of Sodium Salts of Tosylhydrazones of Some Heterocyclic Aldehydes in the Presence of Silver Chromate: 1,3 NÅ®C Migration of Tosyl Group
  作者：Katsuhiro Saito、Hiraku Ishihara

  DOI：10.3987/r-1987-07-1891

  日期：——
• An expeditious synthetic approach towards the synthesis of Bis-Schiff bases (aldazines) using ultrasound
  作者：Khalid M. Khan、Waqas Jamil、Nida Ambreen、Muhammad Taha、Shahnaz Perveen、Guillermo A. Morales

  DOI：10.1016/j.ultsonch.2013.12.011

  日期：2014.5

  Aldazines (Bis-Schiff bases) 1-24 were synthesized using aromatic aldehydes (heterocyclic and benzaldehydes) and hydrazine hydrate under reflux using conventional heating and/or via ultrasound irradiation using BiCl3 as catalyst. Ultrasonication conditions with cat. BiCl3 proved to be an effective, environmentally friendly synthetic procedure. This methodology is robust in the presence of electron donating and electron withdrawing groups affording desired products with high yields (>95%) in just a couple of minutes vs. hours using conventional heating. (C) 2013 Elsevier B.V. All rights reserved.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.1, 2.9.6, page 202 - 206
  作者：

  DOI：——

  日期：——
• Gronowitz,S.; Namtvedt,J., Acta Chemica Scandinavica (1947), 1967, vol. 21, p. 2151 - 2166
  作者：Gronowitz,S.、Namtvedt,J.

  DOI：——

  日期：——
• Bi(thipohene)-type ligand and its silver coordination polymers [AgL2]·(X) (L=1,2-bis((thiophen-3-yl)methylene)hydrazine; )
  作者：Sung Hoon Kim、Soon W. Lee

  DOI：10.1016/j.ica.2007.06.011

  日期：2008.1

  A novel linking ligand, 1,2-bis((thiophen-3-yl)methylene)hydrazine (L), which contains terminal thiophene rings, was prepared. From ligand L and silver salts AgX, the corresponding 2-D silver coordination polymers [AgL2] center dot (X) [X = ClO4- (1), SbF6- (2), PF6- (3)] could be prepared. All polymers have been constructed by van der Waals contacts, and their structures depend basically on the nature of the counterions used. (c) 2007 Elsevier B.V. All rights reserved.