1-Dodecanaminium, N,N,N-trimethyl-, fluoride | 118936-21-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-Dodecanaminium, N,N,N-trimethyl-, fluoride
• 英文别名: dodecyl(trimethyl)azanium;fluoride
• CAS: 118936-21-3
• 化学式: C15H34FN
• 分子量: 247.44
• InChiKey: KLTIXASWUBITSZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.62
• 重原子数：
  17
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Organic metal compound and process for preparing optically-active alcohols using the same
  申请人：Miki Takashi

  公开号：US20090062573A1

  公开（公告）日：2009-03-05

  The present invention provides an asymmetric reduction catalyst effective in preparing optically-active alcohol compounds having various functional groups, and a process for preparing optically-active alcohol compounds using said asymmetric reduction catalyst. The organic metal compound of the present invention is represented by the following general formula (1): wherein R 1 and R 2 may be mutually identical or different, and are an alkyl group, a phenyl group, a naphthyl group, a cycloalkyl group, or an alicyclic ring formed by binding R 1 and R 2 , which may have a substituent; R 3 is a hydrogen atom or an alkyl group; Cp is a cyclopentadienyl group, which may have a substituent, bound to M 1 via a π bond; X 1 is a halogen atom or a hydrido group; M 1 is rhodium or iridium; and * denotes asymmetric carbon.

  本发明提供了一种在制备具有各种官能团的光学活性醇化合物中有效的非对称还原催化剂，以及使用所述非对称还原催化剂制备光学活性醇化合物的方法。 本发明的有机金属化合物由以下通式(1)表示： 其中R1和R2可以相互相同或不同，并且是烷基、苯基、萘基、环烷基或由R1和R2结合形成的脂肪环环，其中可能含有取代基；R3是氢原子或烷基；Cp是环戊二烯基，可能含有取代基，通过π键与M1结合；X1是卤素原子或氢化物基团；M1是铑或铱；*表示不对称碳。
• ASYMMETRIC CATALYST AND PROCESS FOR PREPARING OPTICALLY ACTIVE ALCOHOLS USING THE SAME
  申请人：Watanabe Masahito

  公开号：US20100261924A1

  公开（公告）日：2010-10-14

  The present invention provides an organic metal compound, a ligand, an asymmetric catalyst, and a process for preparing optically-active alcohols using the asymmetric catalyst. The organic metal compound of the present invention is expressed by the following general formula (1): wherein in general formula (1), R 1 and R 2 are a mutually identical or mutually different, unsubstituted or substituted alkyl group, aryl group, cycloalkyl group, or R 1 and R 2 are bound to form an alicyclic ring, R 3 is a hydrogen atom or an alkyl group, R 4 is a branched alkyl group or an alkyl group that does or does not form a ring by itself, or an unsubstituted or substituted aryl group, or an unsubstituted or substituted heterocyclic group, Ar is an unsubstituted or substituted cyclopentadienyl group that is bound to M via a π bond, or an unsubstituted or substituted benzene, X is a hydride group or an anionic group, M is ruthenium, rhodium or iridium, L is a solvent molecule or a water molecule, l is 1 or 2, m is an integer from 0 to 2, n is 0 or 1, and when n is 0, X does not exist, and * represents asymmetric carbon, wherein R 4 is not a camphor group, a camphor derivative group, an isopropyl group or a phenyl group whenever R 1 and R 2 are both a phenyl group.

  本发明提供一种有机金属化合物、配体、不对称催化剂以及利用该不对称催化剂制备光学活性醇的方法。本发明的有机金属化合物由以下通用式（1）表示： 在通用式（1）中，R1和R2是相互相同或相互不同的未取代或取代的烷基基团、芳基团、环烷基团，或R1和R2结合形成脂环，R3是氢原子或烷基基团，R4是支链烷基基团或自身形成环或不形成环的烷基基团，或未取代或取代的芳基团，或未取代或取代的杂环基团，Ar是通过π键与M结合的未取代或取代的环戊二烯基团，或未取代或取代的苯，X是氢化物基团或阴离子基团，M是钌、铑或铱，L是溶剂分子或水分子，l为1或2，m为0到2的整数，n为0或1，当n为0时，X不存在，*代表不对称碳，其中当R1和R2均为苯基团时，R4不是藿香基团、藿香衍生基团、异丙基团或苯基团。
• Calcium peroxyphosphates and use thereof in dental compositions
  申请人：Tung S. Ming

  公开号：US20050281759A1

  公开（公告）日：2005-12-22

  Calcium peroxyphosphate compounds and dental compositions comprising these compounds that combine both whitening/stain removal of teeth with remineralization are disclosed. The calcium peroxyphosphate compounds are capable of releasing, in an aqueous environment, whitening and remineralization effective amounts of calcium ion, phosphate ion, and active oxygen. Preferred compounds are calcium peroxymonophosphate or calcium diperoxymonophosphate compounds. These compounds may be used in humans and other animals, including other mammals.

  本发明揭示了一种含有过氧磷酸钙化合物的牙科组合物，它们结合了牙齿的美白/去污和再矿化。这些过氧磷酸钙化合物能够在水环境中释放出对美白和再矿化有效的钙离子、磷酸离子和活性氧。优选的化合物为过氧单磷酸钙或过氧二磷酸钙化合物。这些化合物可用于人类和其他动物，包括其他哺乳动物。
• CALCIUM PEROXYPHOSPHATES AND USE THEREOF IN DENTAL COMPOSITIONS
  申请人：TUNG MING S.

  公开号：US20110142768A1

  公开（公告）日：2011-06-16

  Calcium peroxyphosphate compounds and dental compositions comprising these compounds that combine both whitening/stain removal of teeth with remineralization are disclosed. The calcium peroxyphosphate compounds are capable of releasing, in an aqueous environment, whitening and remineralization effective amounts of calcium ion, phosphate ion, and active oxygen. Preferred compounds are calcium peroxymonophosphate or calcium diperoxymonophosphate compounds. These compounds may be used in humans and other animals, including other mammals.

  本发明揭示了包含钙过氧磷酸盐化合物的牙科组合物，这些化合物将牙齿的美白/去污和再矿化结合在一起。钙过氧磷酸盐化合物能够在水环境中释放钙离子、磷酸离子和活性氧，以达到美白和再矿化的效果。优选的化合物是钙过氧单磷酸盐或钙过氧双磷酸盐化合物。这些化合物可用于人类和其他动物，包括其他哺乳动物。
• Asymmetric catalyst and process for preparing optically active alcohols using the same
  申请人：Kanto Kagaku Kabushiki Kaisha

  公开号：EP2239057A1

  公开（公告）日：2010-10-13

  The present invention provides an organic metal compound, a ligand, an asymmetric catalyst, and a process for preparing optically-active alcohols using the asymmetric catalyst. The organic metal compound of the present invention is expressed by the following general formula (1): wherein in general formula (1), R1 and R2 are a mutually identical or mutually different, unsubstituted or substituted alkyl group, aryl group, cycloalkyl group, or R1 and R2 are bound to form an alicyclic ring, R3 is a hydrogen atom or an alkyl group, R4 is a branched alkyl group or an alkyl group that does or does not form a ring by itself, or an unsubstituted or substituted aryl group, or an unsubstituted or substituted heterocyclic group, Ar is an unsubstituted or substituted cyclopentadienyl group that is bound to M via a π bond, or an unsubstituted or substituted benzene, X is a hydride group or an anionic group, M is ruthenium, rhodium or iridium, L is a solvent molecule or a water molecule, 1 is 1 or 2, m is an integer from 0 to 2, n is 0 or 1, and when n is 0, X does not exist, and * represents asymmetric carbon, wherein R4 is not a camphor group, a camphor derivative group, an isopropyl group or a phenyl group whenever R1 and R2 are both a phenyl group.

  本发明提供了一种有机金属化合物、一种配体、一种不对称催化剂以及一种使用该不对称催化剂制备光学活性醇的工艺。本发明的有机金属化合物由以下通式（1）表示： 其中通式（1）中，R1 和 R2 是相互相同或相互不同的未取代或取代的烷基、芳基、环烷基，或 R1 和 R2 结合形成脂环，R3 是氢原子或烷基，R4 是支链烷基或本身形成或不形成环的烷基，或未取代或取代的芳基，或未取代或取代的杂环基、Ar 是通过 π 键与 M 结合的未取代或取代的环戊二烯基，或未取代或取代的苯， X 是氢化物基团或阴离子基团，M 是钌、铑或铱，L 是溶剂分子或水分子、1 是 1 或 2，m 是 0 至 2 的整数，n 是 0 或 1，当 n 为 0 时，X 不存在，* 代表不对称碳，其中当 R1 和 R2 都是苯基时，R4 不是樟脑基团、樟脑衍生物基团、异丙基团或苯基。