1-(2-cyanoethyl)-4,8,11-trimethyl-1,4,8,11-tetraazacyclotetradecane

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-(2-cyanoethyl)-4,8,11-trimethyl-1,4,8,11-tetraazacyclotetradecane
• 英文别名: 3-(4,8,11-Trimethyl-1,4,8,11-tetrazacyclotetradec-1-yl)propanenitrile；3-(4,8,11-trimethyl-1,4,8,11-tetrazacyclotetradec-1-yl)propanenitrile
• 化学式: C₁₆H₃₃N₅
• 分子量: 295.472
• InChiKey: PMTMXEAWJVNZCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  36.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  nickel(II) perchlorate hexahydrate 、 1-(2-cyanoethyl)-4,8,11-trimethyl-1,4,8,11-tetraazacyclotetradecane 以 甲醇 为溶剂， 以89%的产率得到(1-(2-cyanoethyl)-4,8,11-trimethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) diperchlorate
  参考文献：
  名称：

  Barefield, E. Kent; Foster, Keith A.; Freeman, Gary M., Inorganic Chemistry, 1986, vol. 25, # 26, p. 4663 - 4668

  摘要：

  DOI：

文献信息

• Method for functionalizing a solid substrate, other than a substrate made of gold, via specific chemical compounds
  申请人：COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES

  公开号：US10002769B2

  公开（公告）日：2018-06-19

  The invention relates to a method for functionalizing an electrically conductive substrate, which is not a substrate made of gold, via a layer of chemical compounds, said method comprising the following steps: a step in which the electrically conductive substrate is placed in contact with chemical compounds comprising at least a disulfide terminal group; a step in which the disulfide terminal group of said chemical compounds is electro-oxidized, causing said chemical compounds to form a layer at the surface of the electrically conductive substrate.

  本发明涉及一种通过一层化合物使导电基底（非金基底）功能化的方法，所述方法包括以下步骤： 将导电基底与至少包含一个二硫终端基团的化合物接触的步骤； 对所述化合物的二硫端基团进行电氧化，使所述化合物在导电基底表面形成一层。
• METHOD FOR FUNCTIONALIZING A SOLID SUBSTRATE, OTHER THAN A SUBSTRATE MADE OF GOLD, VIA SPECIFIC CHEMICAL COMPOUNDS
  申请人：UNIVERSITE JOSEPH FOURIER

  公开号：US20140295213A1

  公开（公告）日：2014-10-02

  The invention relates to a method for functionalizing an electrically conductive substrate, which is not a substrate made of gold, via a layer of chemical compounds, said method comprising the following steps: a step in which the electrically conductive substrate is placed in contact with chemical compounds comprising at least a disulfide terminal group; a step in which the disulfide terminal group of said chemical compounds is electro-oxidized, causing said chemical compounds to form a layer at the surface of the electrically conductive substrate.