申请人:SANYO CHEMICAL INDUSTRIES LTD.
公开号:EP0496067A2
公开(公告)日:1992-07-29
The invention relates to a method for producing formed articles of water-absorbing hydrogel, which comprises the steps of supplying an aqueous solution containing (a) a polymerizable monomer having a hydrophilic functional group, (b) a crosslinking agent and (c) a polymerization initiator to a polymerizing apparatus capable of polymerizing the aqueous solution in a form of layer, subsequently causing constant temperature polymerization of the solution by controlling the temperature of the system being polymerized to 20 to 70 °C without agitating the same, and forming the obtained hydrogel polymer, which has a water content of 20 to 70 % by weight, to any desired shape. Formed articles of the water-absorbing hydrogel have high absorption under non-pressure, high absorption under pressure and easy formability to a desired shape. In addition, there are no problems of pollution of working environments by fine powder. Thus, the formed articles according to the invention are useful for physiological commodities, paper diapers or like sanitary materials, drip absorbing materials, water-blocking materials for construction and civil engneering and so forth.
本发明涉及一种生产吸水性水凝胶成型品的方法,该方法包括以下步骤:将含有(a)具有亲水官能团的可聚合单体、(b)交联剂和(c)聚合引发剂的水溶液提供给能使水溶液聚合成层的聚合装置、随后,通过将聚合体系的温度控制在 20 至 70 °C,在不搅拌的情况下使溶液恒温聚合,并将获得的水凝胶聚合物(按重量计含水量为 20% 至 70%)制成任何所需的形状。吸水性水凝胶的成型品在无压条件下具有高吸水性,在有压条件下具有高吸水性,并且易于成型为所需形状。此外,不会出现细粉末污染工作环境的问题。因此,本发明的成型品可用于生理用品、纸尿布或类似的卫生材料、滴水吸收材料、建筑和土木工程中的阻水材料等。