N,N,N',N'',N'''-hexaethyltriethylenetetramine | 24426-32-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N',N'',N'''-hexaethyltriethylenetetramine
• 英文别名: N,N,N',N",N'",N'"-hexaethyltriethylenetetramine；1,1,4,7,10,10-Hexaethyl-triethylentetramin；N,N,N,N',N''',N'''-hexaethyl-1,4,7,10-tetraazadecane；N,N,N,N,N,N-hexaethyltriethylenetetraamine；N'-[2-[2-(diethylamino)ethyl-ethylamino]ethyl]-N,N,N'-triethylethane-1,2-diamine
• CAS: 24426-32-2
• 化学式: C₁₈H₄₂N₄
• 分子量: 314.558
• InChiKey: DVWXFCMTEPNUMG-UHFFFAOYSA-N

物化性质

• 沸点：
  344.2±10.0 °C(Predicted)
• 密度：
  0.886±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  22
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  13
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N,N',N'',N'''-hexaethyltriethylenetetramine 、 copper(II) sulfate 在 BaI₂ 作用下， 以 甲醇 为溶剂， 生成 Cu(N,N,N,N',N''',N'''-hexaethyl-1,4,7,10-tetraazadecane)I2
  参考文献：
  名称：

  The effect of N-Alkylation on the properties of five-coordinate copper(II) complexes of tetra-amine ligands

  摘要：

  DOI：

  10.1016/s0020-1693(00)87269-2
• 作为产物：
  描述：

  N,N-二乙基乙二胺 、 2-二乙氨基氯乙烷盐酸盐 生成 N,N,N',N'',N'''-hexaethyltriethylenetetramine
  参考文献：
  名称：

  Gelbard,G.; Rumpf,P., Bulletin de la Societe Chimique de France, 1969, p. 1161 - 1170

  摘要：

  DOI：

文献信息

• [EN] METHOD OF PRODUCING POLYALKYLATED OLIGOALKYLENEPOLYAMINES<br/>[FR] PROCÉDÉ DE PRODUCTION D'OLIGOALKYLÈNEPOLYAMINES POLYALKYLÉES
  申请人：NDSU RES FOUNDATION

  公开号：WO2011097490A1

  公开（公告）日：2011-08-11

  A method of preparing polyalkylated oligoalkylenepolyamines is provided. The method includes contacting oligoalkylenepolyamine with a reagent composition comprising (a) alkyl bromide and/or alkyl chloride; (b) a basic agent; and (c) iodide salt. The alkylation reaction may be carried out in a polar, aprotic organic solvent.

  提供了一种制备聚烷基化寡聚烷基乙二胺的方法。该方法包括将寡聚烷基乙二胺与包含（a）烷基溴化物和/或烷基氯化物；（b）一种碱性试剂；和（c）碘化盐的试剂组合物接触。烷基化反应可以在极性、无质子有机溶剂中进行。
• Near infrared radiation-absorbing composition, near infrared radiation cut-off filter and production method therefor, and camera module and production method therefor
  申请人：FUJIFILM Corporation

  公开号：US10184052B2

  公开（公告）日：2019-01-22

  An object of the present invention is to provide a near infrared radiation-absorbing composition having favorable shielding properties in a near infrared range when used to produce cured films, a near infrared radiation cut-off filter and a production method therefor, and a camera module and a production method therefor. The near infrared radiation-absorbing composition including a copper complex formed by reacting a compound (A) having two or more coordinating atoms that form bonds using unshared electron pairs with a copper component.

  本发明的目的是提供一种在用于生产固化薄膜时在近红外范围内具有良好屏蔽性能的近红外辐射吸收组合物、一种近红外辐射截止滤光片及其生产方法，以及一种相机模组及其生产方法。近红外辐射吸收组合物包括铜络合物，该铜络合物是由具有两个或两个以上配位原子的化合物（A）与铜成分反应形成的，该化合物具有两个或两个以上配位原子，这些配位原子利用未共享电子对形成键。
• Transalkylation reaction. Homogeneous catalytic formation of carbon-nitrogen bonds
  作者：Robert B. Wilson、Richard M. Laine

  DOI：10.1021/ja00288a015

  日期：1985.1
• Zagudullin, R. N.; Baimetov, Z. M., Journal of general chemistry of the USSR, 1991, vol. 61, # 4.2., p. 889 - 894
  作者：Zagudullin, R. N.、Baimetov, Z. M.

  DOI：——

  日期：——
• NEAR INFRARED RADIATION-ABSORBING COMPOSITION, NEAR INFRARED RADIATION CUT-OFF FILTER AND PRODUCTION METHOD THEREFOR, AND CAMERA MODULE AND PRODUCTION METHOD THEREFOR
  申请人：FUJIFILM Corporation

  公开号：US20160304730A1

  公开（公告）日：2016-10-20

  An object of the present invention is to provide a near infrared radiation-absorbing composition having favorable shielding properties in a near infrared range when used to produce cured films, a near infrared radiation cut-off filter and a production method therefor, and a camera module and a production method therefor. The near infrared radiation-absorbing composition including a copper complex formed by reacting a compound (A) having two or more coordinating atoms that form bonds using unshared electron pairs with a copper component.