N,N,N-Tri(propan-2-yl)propan-2-aminium iodide | 29171-32-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N-Tri(propan-2-yl)propan-2-aminium iodide
• 英文别名: tetra(propan-2-yl)azanium;iodide
• CAS: 29171-32-2
• 化学式: C12H28IN
• 分子量: 313.26
• InChiKey: BRZRAZAEOUQSRE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.44
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• Process for producing chromone compound
  申请人：Hibino Hiroaki

  公开号：US20050085664A1

  公开（公告）日：2005-04-21

  A process for producing a dicarboxylic acid compound represented by the formula (4): wherein R 1 and R 2 are the same or different and each represents lower alkyl and the wavy line indicates that this compound is the E- or Z-isomer or a mixture of them, characterized by reacting a compound represented by the formula (2): wherein R 1 , R 2 and the wavy line have the same meanings as the above, and one of X 2 and X 3 represents hydrogen and the other represents halogen, with nitrophenol represented by the formula (3): in the presence of a base; a process for producing a nitrochromone compound represented by the formula (5): wherein R 1 has the same meaning as the above, characterized by reacting the dicarboxylic acid compound or carboxylic acid thereof with an acid; a process for producing an aminochromone compound which comprises reducing the nitrochromone compound; and a process for producing an amidochromone compound which comprises acylating the aminochromone compound are provided.

  提供一种制备式（4）的二羧酸化合物的方法，其中R1和R2相同或不同，每个代表低级烷基，波浪线表示该化合物是E或Z异构体或它们的混合物，其特征在于将式（2）的化合物与硝基酚在碱的存在下反应，式中R1、R2和波浪线的含义与上述相同，X2和X3中的一个代表氢，另一个代表卤素；提供一种制备式（5）的硝基香豆素化合物的方法，其中R1的含义与上述相同，其特征在于将二羧酸化合物或其羧酸与酸反应；提供一种制备氨基香豆素化合物的方法，其包括还原硝基香豆素化合物；以及提供一种制备酰胺香豆素化合物的方法，其包括酰化氨基香豆素化合物。
• Process for the preparation of carboxylic acids
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0118151A1

  公开（公告）日：1984-09-12

  A process for the preparation of a carboxylic acid RCOOH wherein R represents an alkyl, cycloalkyl or aralkyl group by heating an ester of formic acid HCOOR in the presence of carbon monoxide, a soluble rhodium catalyst and an iodide and/or bromide source, characterized in that a compound of the formula wherein X represents phosphorus, arsenic or antimony and Y oxygen, sulphur or selenium and R' represents hydrogen or an unsubstituted or substituted hydrocarbyl group and either a and b independently are 0 or 1 and R2 and R3 each represent an unsubstituted or substituted hydrocarbyl group, or a and b are both 0 and R2 and R3 together with X form a heterocylic group, or a complex of a compound of formula I with a hydrocarbon iodide or bromide, and acyl iodide or bromide or a hydrogen iodide or bromide is present in the reaction mixture as promoter.

  一种制备羧酸 RCOOH（其中 R 代表烷基、环烷基或芳烷基）的工艺，其方法是在一氧化碳、可溶性铑催化剂和碘源和/或溴源存在下加热甲酸酯 HCOOR，其特征在于式中的化合物 其中 X 代表磷、砷或锑，Y 代表氧、硫或硒，R'代表氢或未取代或取代的烃基，a 和 b 分别为 0 或 1，R2 和 R3 分别代表未取代或取代的烃基、或 a 和 b 均为 0，且 R2 和 R3 与 X 共同形成杂环基，或式 I 化合物与烃碘化物或溴化物的络合物，以及酰基碘化物或溴化物或氢碘化物或溴化物作为促进剂存在于反应混合物中。
• A process for the preparation of carboxylic acids and/or esters
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0124160A1

  公开（公告）日：1984-11-07

  Process for the preparation of carboxylic acids and/or esters by reacting an alcohol with carbon monoxide in the presence of a homogeneous palladium-containing catalyst, an iodide and/or bromide source and an organo-nitrogen compound, characterized in that an organo-nitrogen compound containing an group (X being oxygen or sulphur) in a quantity of at least 0.3 mol per mol alcohol is used as promoter.

  在均相含钯催化剂、碘化源和/或溴化源以及有机氮化合物存在下，通过使醇与一氧化碳反应制备羧酸和/或酯的工艺，其特征在于，以每摩尔醇中含有至少 0.3 摩尔基团（X 为氧或硫）的有机氮化合物作为促进剂。 基团（X 为氧或硫）的有机氮化合物作为促进剂，其含量至少为 0.3 摩尔/摩尔醇。
• PROCESS FOR PRODUCING CHROMONE COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1479667A1

  公开（公告）日：2004-11-24

  A process for producing a dicarboxylic acid compound represented by the formula (4): wherein R1 and R2 are the same or different and each represents lower alkyl and the wavy line indicates that this compound is the E- or Z-isomer or a mixture of them, characterized by reacting a compound represented by the formula (2): wherein R1, R2 and the wavy line have the same meanings as the above, and one of X2 and X3 represents hydrogen and the other represents halogen, with nitrophenol represented by the formula (3): in the presence of a base; a process for producing a nitrochromone compound represented by the formula (5): wherein R1 has the same meaning as the above, characterized by reacting the dicarboxylic acid compound or carboxylic acid thereof with an acid; a process for producing an aminochromone compound which comprises reducing the nitrochromone compound; and a process for producing an amidochromone compound which comprises acylating the aminochromone compound are provided.

  一种生产由式(4)代表的二羧酸化合物的工艺： 其中 R1 和 R2 相同或不同，且各自代表低级烷基，波浪线表示该化合物为 E-或 Z-异构体或它们的混合物，其特征在于使式（2）所代表的化合物反应： 其中 R1、R2 和波浪线的含义与上述相同，X2 和 X3 中的一个代表氢，另一个代表卤素： 在碱存在下；生产式（5）代表的硝基色酮化合物的工艺： 其中 R1 的含义与上述相同，其特征在于使二羧酸化合物或其羧酸与酸反应；提供了一种生产氨基色素化合物的工艺，该工艺包括还原硝基色素化合物；以及一种生产氨基色素化合物的工艺，该工艺包括酰化氨基色素化合物。
• Process for Producing Chromone Compound
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2105431A1

  公开（公告）日：2009-09-30

  A process for producing a dihalosuccinic acid compound in which the proportion of a threo-dihalosuccinic acid compound is 70% or higher, which comprises adding a maleic acid compound to a halogenating agent.

  一种生产二卤代琥珀酸化合物的工艺，其中三卤代二卤代琥珀酸化合物的比例为 70% 或更高，该工艺包括在卤化剂中加入马来酸化合物。