2,2,3,3,5,5,6,6-octafluoro-4-(1,2,2-trifluorovinyl)morpholine | 39650-43-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2,2,3,3,5,5,6,6-octafluoro-4-(1,2,2-trifluorovinyl)morpholine
• 英文别名: Perfluor-(N-vinylmorpholin)；4-(Trifluoroethenyl)-2,2,3,3,5,5,6,6-octafluoromorpholine；2,2,3,3,5,5,6,6-octafluoro-4-(1,2,2-trifluoroethenyl)morpholine
• CAS: 39650-43-6
• 化学式: C₆F₁₁NO
• 分子量: 311.055
• InChiKey: FYWMUSXBRBQLJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  19
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  13

反应信息

• 作为反应物：
  描述：

  2,2,3,3,5,5,6,6-octafluoro-4-(1,2,2-trifluorovinyl)morpholine 在 sodium tetrahydroborate 作用下， 以 二乙二醇二甲醚 为溶剂， 反应 0.5h， 生成 4-(1,2-difluorovinyl)-2,2,3,3,5,5,6,6-octafluoromorpholine
  参考文献：
  名称：

  [EN] HYDROFLUOROOLEFINS AND METHODS OF USING SAME
  [FR] HYDROFLUOROLÉFINES ET PROCÉDÉS D'UTILISATION ASSOCIÉS

  摘要：

  以下是通式（I）所代表的一种氢氟烯烃化合物： (I) 其中，Rf1和Rf2，以及Rf3和Rf4，分别是（i）独立的线性或支链氟代烷基，具有1-8个碳原子，且可选地包含至少一个选自O或N的连锁杂原子；或（ii）相互连接形成含有4-8个碳原子的环结构，且可选地含有一个或多个选自O或N的连锁杂原子。X为CF3、H或F；而Z为F或H。

  公开号：

  WO2018116159A1
• 作为产物：
  描述：

  2-morpholinopropionic acid methyl ester 在 potassium carbonate 作用下， 生成 2,2,3,3,5,5,6,6-octafluoro-4-(1,2,2-trifluorovinyl)morpholine
  参考文献：
  名称：

  通过全氟（2-二烷基氨基丙酸）碱金属盐的热解反应制备全氟乙烯基胺的新途径

  摘要：

  描述了获得各种全氟乙烯基胺的潜在通用途径，包括全氟（2-二烷基氨基丙酸）碱金属盐的热解

  DOI：

  10.1246/cl.1988.1887

文献信息

• N-fluoro-compounds. Part V. Photochemical reactions of perfluoro-N-fluoromorpholine, and a re-investigation of its thermal decomposition; preparation and properties of perfluoromorpholin-N-oxyl
  作者：R. E. Banks、A. J. Parker、M. J. Sharp、G. F. Smith

  DOI：10.1039/p19730000005

  日期：——

  perfluoromorpholyl nitrite, perfiuoro-[1,2-bis(morpholino-oxy)ethane], and perfiuoro-[N-(morpholino-oxy)morpholine] and perfluorobiacetyl, respectively. Flow pyrolysis of perfluoro-N-fluoromorpholine in platinum yields carbonyl fluoride, carbon tetrafluoride, hexafluoroethane, perfluoro-2-azapropene, perfluoro-2-azabut-2-ene. perfluoro-(N-methyloxazolidine), perfluoro-5,6-dihydro-2H-1,4-oxazine, and, possibly, N-f

  在全氟环丁烯的存在下对全氟-N-氟吗啉进行紫外线照射会产生全氟双环丁基，全氟-NN'-双吗啉基和全氟-（N-环丁基吗啉）。最后产物的热解产生全氟-（N-乙烯基吗啉），其光化学溴化反应生成全氟-[ N-（1,2-二溴乙基）-吗啉]，该化合物也与N-（2-bromo-1）一起形成（1，2，2-三氟乙基）八氟吗啉，当乙烯基衍生物进行光化学加氢溴化时。紫外线照射在二氧化硅的Pyrex全氟的装置Ñ -fluoromorpholine，单独或氧，产率，存在特别，N–O–N化合物全氟-[ N-（吗啉代-氧基）吗啉]。此产物的热解给出perfluoromorpholin- Ñ -1-氧基，perfiuoro- NN' -bimorpholyl，perfiuoro-（6-吗啉代氧-2-氮杂-5- oxahex -1-烯），perfiuoro-（6-吗啉代氧基-2- -aza-5-oxahex-2-ene），全氟-5
• NITROGEN CONTAINING HYDROFLUOROETHERS AND METHODS OF USING SAME
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20170283365A1

  公开（公告）日：2017-10-05

  A hydrofluoroether compound is represented by the following general formula (1): wherein n is 1-2.

  氢氟醚化合物由以下一般式（1）表示：其中n为1-2。
• [EN] AMINE-CONTAINING CYCLIC HYDROFLUOROETHERS AND METHODS OF USING THE SAME<br/>[FR] HYDROFLUOROÉTHERS CYCLIQUES CONTENANT UNE AMINE ET LEURS PROCÉDÉS D'UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2017155735A1

  公开（公告）日：2017-09-14

  Described herein is a cyclic fluorinated compound of formula (I) where: L is O, CH2, or a covalent bond; X is selected from F or CF3, and Y is selected from H, F, or CF3, wherein when X is CF3 then Y is F and when Y is CF3 then X is F„ each Rf1 is independently selected from a linear or branched perfluorinated alkyl group comprising 1-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof; or the two Rf1 groups are bonded together to form a fluorinated ring structure comprising 4-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof; the -CFZ-CHAQ group is bonded to a ring carbon that is alpha to at least one O atom of the ring; A is selected from F, or CF3; Z is selected from H, F, or CF3; and Q is selected from (i) a F atom, (ii) a Cl atom, (iii) a linear, cyclic, or branched perfluorinated alkyl group comprising 1-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof, or (iv) a G(Rf2)e group, where G is an O atom or a N atom wherein: when Q is a Cl atom, then Z and A are F atoms; when G is O then e is 1, Z is H, F, or CF3; A is F; and Rf2 is a linear or branched perfluorinated alkyl group comprising 1-10 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof; when G is N then e is 2, and each Rf2 group is independently a linear or branched perfluorinated alkyl group comprising 1-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof or the two Rf2 groups are bonded together to form a fluorinated ring structure comprising 4-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof, with the proviso that when A is CF3 then Z is F, and when Z is CF3 then A is F.

  本文描述的是一个循环氟化合物，其化学式为(I)，其中：L为O、CH2或共价键；X从F或CF3中选择，Y从H、F或CF3中选择，当X为CF3时，Y为F，当Y为CF3时，X为F；每个Rf1独立地选择自由1-8个碳原子的线性或支链全氟烷基基团，并且可选地包含至少一个由O、N或其组合选择的连结原子；或两个Rf1基团结合在一起形成含有4-8个碳原子并且可选地包含至少一个由O、N或其组合选择的连结原子的氟化环结构；-CFZ-CHAQ基团与环的至少一个O原子的α位碳原子结合；A从F或CF3中选择；Z从H、F或CF3中选择；Q从(i)F原子、(ii)Cl原子、(iii)线性、环状或支链全氟烷基基团，包括1-8个碳原子，并且可选地包含至少一个由O、N或其组合选择的连结原子，或(iv)G(Rf2)e基团中选择，其中G为O原子或N原子，当Q为Cl原子时，Z和A为F原子；当G为O时，e为1，Z为H、F或CF3，A为F，Rf2为包括1-10个碳原子的线性或支链全氟烷基基团，并且可选地包含至少一个由O、N或其组合选择的连结原子；当G为N时，e为2，每个Rf2基团独立地选择自由1-8个碳原子的线性或支链全氟烷基基团，并且可选地包含至少一个由O、N或其组合选择的连结原子，或两个Rf2基团结合在一起形成含有4-8个碳原子并且可选地包含至少一个由O、N或其组合选择的连结原子的氟化环结构，但A为CF3时，Z为F，Z为CF3时，A为F。
• Novel Photochromic Conducting Polymer Having Diarylethene Derivative in the Main Chain
  作者：Tsuyoshi Kawai、Tomokatsu Kunitake、Masahiro Irie

  DOI：10.1246/cl.1999.905

  日期：1999.9

  A conducting polymer having photochromic diarylethene units in the main chain was synthesized. Reversible photochromism was observed in solid film, and photoluminescence and electrical conductivity were found to change along with the photoisomerization.

  合成了主链上具有光致变色二芳基乙烯单元的导电聚合物。在固体薄膜中观察到可逆的光致变色现象，并且发现光致发光和电导率随着光异构化而变化。
• Pyrolysis of perfluoro(dimethylaminoacetic) acid alkali salts
  作者：Masakazu Nishida、Haruhiko Fukaya、Eiji Hayashi、Takashi Abe

  DOI：10.1016/s0022-1139(99)00022-6

  日期：1999.6

  Thermal decomposition of perfluoro(dimethylaminoacetic) acid alkali salts was carried out at 220–310°C. A potassium salt gave CF3NCF2 as the principal product in moderate yield, together with CF3NCFCF3 and (CF3)2NCFCF2. Sodium and lithium salts gave (CF3)2NCFCFN(CF3)2 and (CF3)2NCF2C(O)X (X=F, OH) as the main products.

  全氟（二甲基氨基乙酸）酸碱盐的热分解在220–310°C下进行。A的钾盐，得到CF 3 NCF 2如在中等产率的主要产物，用CF一起3 NCFCF 3和（CF 3）2 NCFCF 2。钠和锂盐，得到（CF 3）2 NCFCFN（CF 3）2和（CF 3）2 NCF 2 C（O）X（X = F，OH）为主要产品。